Triazine-substituted herbicidal azobenzenesulfonamides

ABSTRACT

Triazine-substituted azobenzenesulfonamides useful as preemergent and postemergent herbicides, selected from compounds of Formulae I or II ##STR1## or agriculturally suitable salts thereof, wherein R, R 1 , R 2 , R 3  and A are as defined herein.

This is a division of application Ser. No. 650,188, filed on Sept. 13, 1984, now U.S. Pat. No. 4,585,470.

BACKGROUND OF THE INVENTION

Benzenesulfonamides having a nitrogen-containing substituents on the benzene ring are known as being herbicidal. For example, U.S. Pat. No. 4,369,058 discloses herbicidal benzenesulfonamides of the general formula ##STR2## where R₁ is H, Cl, Br, F, C₁ -C₄ alkyl, OCH₃ or NO₂ ; and

R₂ is NCO, NHCO₂ R₃, NHCOSR₃, NHCOR₃, NHCONR₄ R₅ or NR₆ R₇.

European Patent Application (EP-A) No. 102,924 discloses herbicidal azidobenzenesulfonamides of the formula ##STR3## where R₁ is H, halo, NO₂, C₁ -C₄ alkyl, C₁ -C₄ haloalkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, C₁ -C₄ alkoxycarbonyl, C₁ -C₄ alkylthio, C₁ -C₄ alkylsulfinyl, C₁ -C₄ alkylsulfonyl or C₂ -C₅ alkoxyalkoxy.

The present invention provides a novel class of benzenesulfonamides.

SUMMARY OF THE INVENTION

This invention pertains to novel compounds of Formulae I and II, agriculturally suitable compositions containing them and their method of use as general and/or selective, preemergent and postemergent herbicides. ##STR4## wherein R is H or CH₃ ;

R₁ is NR₄ R₅, N(CH₃)OR₆, NHCN, NRA, P(W)R₄ (W₁ R₅), P(W)(W₁ R₄)(W₂ R₅), P⁺ (C₆ H₅)₃, P⁺ R₆ R₇ R₈, SR₉, SO₂ R₉, C(R₁₀)(R₁₁)NO₂, CH(CN)₂ or Q;

Q is ##STR5## R₂ is H, F, Cl, Br, OCH₃, OC₂ H₅, OCF₂ H, SCH₃, N(CH₃)₂, NO₂, CH₃ or CF₃ ;

R₃ is H, F, Cl, Br, C₁ -C₄ alkyl, CO₂ R₁₅, NO₂, CF₃, C₁ -C₄ alkoxy, C₁ -C₄ alkylthio, SO₂ NR₁₆ R₁₇, C₁ -C₄ alkylsulfonyl, C₁ -C₄ haloalkoxy, C₁ -C₄ alkylsulfonyloxy, C₂ -C₅ alkoxyalkyl or C₃ -C₄ alkenyloxy;

R₄ and R₅ are independently C₁ -C₄ alkyl, C₂ -C₄ alkyl substituted by 1 atom of Br or 1-3 atoms of F or Cl, C₃ -C₅ alkenyl, C₃ -C₅ cycloalkyl, OH, OCH₃, CH₂ OH, CH₂ OR₆, or CH₂ CH₂ OR₆ ; or

R₄ and R₅ may be taken together as --(CH₂)₄ --, --(CH₂)₅ -- or --(CH₂)₂ O(CH₂)₂ --;

R₆ is C₁ -C₆ alkyl;

R₇ and R₈ are independently C₁ -C₄ alkyl;

R₉ is C₁ -C₄ alkyl, phenyl or phenyl substituted with 1-3 atoms of F, Cl or 1 Br;

R₁₀ and R₁₁ are independently H, C₁ -C₄ alkyl, phenyl or phenyl substituted with 1 atom of Br or 1-3 atoms of F or Cl;

R₁₂ is C₁ -C₄ alkyl, C₁ -C₄ alkoxy or NHR₉ ;

R₁₃ and R₁₄ are independently H, C₁ -C₃ alkyl, OR₆, SR₆, NHC(O)R₆, F, Cl, Br or CO₂ R₆ ;

R₁₅ is C₁ -C₄ alkyl, C₃ -C₄ alkenyl, CH₂ CH₂ Cl or CH₂ CH₂ OCH₃ ;

R₁₆ and R₁₇ are independently C₁ -C₂ alkyl;

W is O or S;

W₁ and W₂ are independently O, S or NH;

A is ##STR6## X is CH₃, OCH₃, OCH₂ CH₃, Cl, F, Br, I, OCF₂ H, CH₂ F, OCH₂ CH₂ F, OCH₂ CHF₂, OCH₂ CF₃ or CF₃ ;

Y is H, C₁ -C₃ alkyl, OCH₃, OC₂ H₅, CH₂ OCH₃, NHCH₃, N(OCH₃)CH₃, N(CH₃)₂, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, CH₂ OCH₂ CH₃, OCH₂ CH₂ OCH₃, CH₂ SCH₃, ##STR7## OCF₂ H, SCF₂ H or cyclopropyl; m is 2 or 3;

L₁ and L₂ are independently O or S;

R₁₈ is H or CH₃ ;

Z is CH or N;

Y₁ is O or CH₂ ;

X₁ is CH₃, OCH₃, OC₂ H₅ or OCF₂ H; and

Y₂ is H or CH₃ ;

provided that

(a) when X is Cl, F, Br or I, then Z is CH and Y is OCH₃, OC₂ H₅, N(OCH₃)CH₃, NHCH₃, N(CH₃)₂ or OCF₂ H;

(b) when either X or Y is OCF₂ H, then Z is CH; and

(c) when Q is Q-11 or Q-12, then R₁₃ is other than H;

and their agriculturally suitable salts.

Preferred for reason of increased ease of synthesis and/or greater herbicidal efficacy are:

(1) Compounds of Formulae I or II where R is H and A is A-1;

(2) Compounds of Preferred 1 where X is CH₃, OCH₃ or Cl and Y is CH₃, OCH₃, OC₂ H₅ or CH₂ OCH₃ ; and

(3) Compounds of Preferred 2 where R₂ is H, Cl, CH₃ or OCH₃ and R₃ is Cl, C₁ -C₃ alkyl, C₁ -C₃ alkoxy, NO₂, CO₂ (C₁ -C₃ alkyl), SO₂ N(CH₃)₂, OSO₂ CH₃, OSO₂ C₂ H₅, SO₂ CH₃, SO₂ C₂ H₅ or allyloxy.

Specifically preferred for reason of greatest ease of synthesis and/or greatest herbicidal efficacy are:

2-[4-(dimethylamino)phenylazo]-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide;

[[2-[[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]phenyl]azo]phosphoric acid, dimethylester; and

2-(dimethyl-1-triazeno)-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide.

DETAILED DESCRIPTION OF THE INVENTION Synthesis

Compounds of Formulae I and II can be prepared from the corresponding amino compounds of Formula III by diazotization and coupling with the appropriate reagent as illustrated in Equation 1. ##STR8## Diazotization can be carried out in a mixture of acetic and propionic acid to allow lower temperatures and aid in solution of the amine. Sodium nitrite and sufficient hydrochloric acid and water to promote rapid diazotization are added and the mixture held at -10° to 25° C. for 30 minutes to 10 hours.

Alternatively, the esters of nitrous acid, such as n-butylnitrite and amylnitrite may be used to effect diazotization in organic solvents such as alcohols, acetic acid, dioxane and other media.

These and other methods of diazotization are extensively reviewed by H. Zollinger, "Azo and Diazo Chemistry, Aliphatic and Aromatic Compounds", Interscience Publishers, Inc., New York, N.Y. 1961, pp. 13-23 and S. Patai, Editor, "The Chemistry of Diazonium and Diazo Groups", Part II, John Wiley and Sons, New York, N.Y. 1978, pp. 645-659.

Compounds of Formulae I and II can also be prepared by reaction of the appropriate azobenzenesulfonamide (V) with the phenylcarbamate of the heterocyclic amine (VI) in the presence of one equivalent of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as shown in Equation 2. ##STR9##

The reaction of Equation 2 is preferably carried out by methods analogous to those described in European Patent Application (EP-A) No. 85,028. The phenylcarbamates of Formula VI can be prepared by the reaction of an appropriate heterocyclic amine of Formula ANH₂ with diphenylcarbonate or phenylchloroformate in the presence of a suitable base by methods known to those skilled in the art.

Azobenzenesulfonamides of Formula V can be prepared from the corresponding aminosulfonamides of Formula VII as shown below in Equation 3. ##STR10## Diazotization can be carried out as described for Equation 1 above.

The coupling of the diazonium salt intermediates IV or VIII with a primary or secondary amine to produce a triazene where R₁ is NR₄ R₅, N(CH₃)OR₆, NHCN, NRA, ##STR11## is discussed in the two previous references, Zollinger, p. 177 and Patai, p. 247. The coupling to active methylene compounds where R₁ is C(R₁₀)(R₁₁)NO₂, CH(CN)₂ or Q where Q is Q-1, Q-2, Q-3, Q-4, Q-5, Q-6 and Q-7 is discussed in Zollinger, p. 199 and Patai, 268. Coupling with sulfur compounds where R₁ is SR₉, SO₂ R₉, and SO₂ OR₉ is discussed in Zollinger, p. 150 and Patai, p. 260. Coupling with phosphorous compounds where R₁ is P(W)R₄ (W₁ R₅), P(W)(W₁ R₄)(W₂ R₅), P⁺ (Ph)₃, P⁺ R₆ R₇ R₈ is discussed in Zollinger, p. 152 and by F. Suckfull and H. Haubrich, Angew Chem. 70(8) 238 (1958). Coupling with active aromatic ring systems where R₁ is Q-9, Q-10, Q-11, Q-12, Q-13 and Q-14 is well known in the art of dye preparation, as shown for example in H. A. Lubs, Editor, "The Chemistry of Synthetic Dyes and Pigments" Reinhold Publishing Corp., New York, 1955.

Methods suitable for the preparation of amino compounds of Formulae III and VII can be found in U.S. Pat. Nos. 4,225,337 and 4,369,058. Minor modifications of these methods, where appropriate, would be obvious to one skilled in the art.

The synthesis of heterocyclic amine derivatives has been reviewed in "The Chemistry of Heterocyclic Compounds," a series published by Interscience Publ., New York and London. 2-Aminopyrimidines are described by D. J. Brown in "The Pyrimidines", Vol. XVI of the above series. 2-Amino-1,3,5-triazine can be synthesized according to the methods described by E. M. Smolin and L. Rapaport in "s-Triazines and Derivatives," Vol. XIII of the same series. The synthesis of bicyclic pyrimidineamines is described in U.S. Pat. No. 4,339,267. The preparation of pyrimidines and triazines with acetal and ketal substituents is described in European Patent Application (EP-A) No. 84,224 and cyclopropyl substituted systems are taught in EP-A No. 108,708.

Agriculturally suitable salts of compounds of Formulae I or II are also useful herbicides and can be prepared in a number of ways known to the art. For example, metal salts can be made by contacting compounds of Formulae I or II with a solution of an alkali or alkaline earth metal salt having a sufficiently basic anion (e.g., hydroxide, alkoxide, carbonate or hydroxide). Quaternary amine salts can be made by similar techniques.

Salts of compounds of Formula I or II can also be prepared by exchange of one cation for another. Cationic exchange can be effected by direct contact of an aqueous solution of a salt of a compound of Formulae I or II (e.g., alkali or quaternary amine salt) with a solution containing the cation to be exchanged. This method is most effective when the desired salt containing the exchanged cation is insoluble in water and can be separated by filtration.

Exchange can also be effected by passing an aqueous solution of a salt of a compound of Formulae I or II (e.g., an alkali metal or quaternary amine salt) through a column packed with a cation exchange resin containing the cation to be exchanged for that of the original salt and the desired product is eluted from the column. This method is particularly useful when the desired salt is water-soluble.

Acid addition salts useful in this invention can be obtained by reacting a compound of Formulae I or II with a suitable acid, e.g., p-toluenesulfonic acid, trichloroacetic acid or the like.

The synthesis of compounds described in this invention are further illustrated by the following Examples 1 through 3.

EXAMPLE 1 2-(Dimethyl-1-triazeno)-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide

2-Amino-N-[(4-methoxy-6-methylpyrimidin-2-yl)-aminocarbonyl]benzenesulfonamide (3.0 g) in acetic acid (30 mL), propionic acid (20 mL), water (10 mL) and concentrated HCl (2.0 mL) was cooled to 0° C. To this mixture was added sodium nitrite (0.75 g) with stirring. The mixture was held at -10° to 0° C. for 45 minutes. The mixture was then added to an ice and water slurry containing dimethylamine (150 mL, 25% dimethylamine in water). The homogeneous solution was acidified with acetic acid and the heavy white precipitate filtered, washed with water and dried in vacuo, to afford 2.94 g of the title compound as a white solid, m.p. 158°-160° C.

IR: 1705 cm⁻¹, 1620 cm⁻¹.

NMR (CDCl₃): δ 2.4 (s, 3), 3.3 (d, 6), 3.9 (s, 3), 6.3 (s, 1), 7.2-7.7 (m, 3) and 8.3 (d, 1).

EXAMPLE 2 [[2-[[(4-Methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]phenyl]azo]phosphoric acid, dimethyl ester

2-Amino-N-[(4-methoxy-6-methylpyrimidin-2-yl)-aminocarbonyl]benzenesulfonamide (2.0 g) in acetic acid (20 mL) and propionic acid (10 mL) was treated with concentrated hydrochloric acid (1.0 mL) at 0° C. A thick precipitate formed immediately. Sodium nitrite was added (0.41 g) and the slurry rapidly thinned and was stirred at -10° to 0° C. for 1 hour. To the homogeneous solution was added dimethylphosphite (1.0 mL) and enough sodium hydroxide to raise the pH to 7.0. After stirring for 30 minutes, the mixture was diluted with water and extracted with ethyl acetate, water washed, dried and evaporated to a red oil. Chromatography gave a pure fraction of 0.28 g of the title compound, m.p. 155°-156° C.

IR: 3300 cm⁻¹, 1710 cm⁻¹ ; 1700 cm⁻¹.

NMR (CDCl₃): δ 2.4 (s, 3), 3.9 (s, 3), 3.95 (d, 6), 6.25 (s, 1), 7.2 (m, 1), 7.5 (m, 1), 7.8 (m, 1) and 8.45 (m, 1).

EXAMPLE 3 2-[(4-Dimethylamino)phenylazo]-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide

2-Amino-N-[(4-methoxy-6-methylpyrimidin-2-yl)-aminocarbonyl]benzenesulfonamide (1.0 g) in acetic acid (25 mL) was treated with n-butyl nitrite (0.31 g) at 25° C. for 3 hours. The solution became homogeneous on addition of the n-butyl nitrite. N,N-Dimethylaniline (0.5 g) was then added and the mixture stirred at 25° C. for 2 hours. The fine orange crystals were filtered and water washed and dried to afford 0.47 g of the title compound, m.p. 210°-211° C. A second crop was isolated from the filtrate, 0.2 g, m.p. 198°-204° C.

IR: 1710 cm⁻¹.

NMR (TFA): δ 2.6 (s, 3), 3.6 (s, 6), 4.2 (s, 3), 6.6 (s, 1) and 7.2-8.2 (m, 8).

Using the procedures of Examples 1-3, and the synthetic routes disclosed herein, the compounds of Tables I-XXXII can be prepared. ##STR12##

                                      TABLE I                                      __________________________________________________________________________     General Formula I                                                              R  R.sub.1       R.sub.2                                                                              X      Y          Z  m.p. (°C.)                  __________________________________________________________________________     H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              CH.sub.3   CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              OCH.sub.3  CH 158-160                            H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              CH.sub.3   N                                     H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              OCH.sub.3  N                                     H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                             OCH.sub.3  N                                     CH.sub.3                                                                          N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            6-F   OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            6-Cl  OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            6-Br  OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            5-OCH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            5-F   OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            3-OC.sub.2 H.sub.5                                                                   OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            6-OCF.sub.2 H                                                                        OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            5-SCH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            5-N(CH.sub.3).sub.2                                                                  OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            5-NO.sub.2                                                                           OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            6-CH.sub.3                                                                           OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            6-CF.sub.3                                                                           OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(C.sub.2 H.sub.5).sub.2                                                                     H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3)C.sub.4 H.sub.9                                                                   H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3)CH.sub.2 CF.sub.3                                                                 H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.2 CH.sub.2 Cl).sub.2                                                                H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3)CH.sub.2 CH.sub.2 Br                                                              H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3)CH.sub.2 CHCH.sub.2                                                               H     OCH.sub.3                                                                             OCH.sub.3  CH                                                     H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(OH)CH.sub.3 H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(OCH.sub.3)CH.sub.3                                                                         H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3)CH.sub.2 OH                                                                       H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3)CH.sub.2 OCH.sub.3                                                                H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3)(cyclopropyl)                                                                     H     OCH.sub. 3                                                                            OCH.sub.3  CH                                    H  N(CH.sub.3)(cyclopentyl)                                                                     H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H                                                                                  ##STR13##    H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H                                                                                  ##STR14##    H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H                                                                                  ##STR15##    H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                       H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.3).sub.2                                                H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3)OC.sub.4 H.sub.9                                                                  H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  NHCN          H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H                                                                                  ##STR16##    H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  P(O)(OCH.sub.3).sub.2                                                                        H     CH.sub.3                                                                              OCH.sub.3  CH 155-156                            H  P(O)(CH.sub.3)OCH.sub.3                                                                      H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  P(O)(CH.sub.2 CF.sub.3)OCH.sub. 3                                                            H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  P(O)(OCH.sub.3)CH.sub.2 CHCH.sub.2                                                           H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  P(S)(CH.sub.3)OCH.sub.3                                                                      H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  P(O)(CH.sub.3)SCH.sub.3                                                                      H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  P(O)(CH.sub.3)NHCH.sub.3                                                                     H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H                                                                                  ##STR17##    H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  P(O)(OCH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                   H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  P(O)(OCH.sub.3)cyclopropyl                                                                   H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  P.sup.+ ( -n-C.sub.4 H.sub.9).sub.3                                                          H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  P.sup.+ (CH.sub.3)(C.sub.2 H.sub.5).sub.2                                                    H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  SCH.sub.3     H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  S -n-C.sub.4 H.sub.9                                                                         H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  SC.sub.6 H.sub.5                                                                             H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  S(3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                              H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  S(4-C.sub.6 H.sub.4 Cl)                                                                      H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  S(2-C.sub.6 H.sub.4 Br)                                                                      H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  SO.sub.2 CH.sub.3                                                                            H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  SO.sub.2 -n-C.sub.4 H.sub.9                                                                  H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  SO.sub.2 C.sub.6 H.sub.5                                                                     H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  SO.sub.2 (3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                      H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  SO.sub.2 (4-C.sub.6 H.sub.4 Cl)                                                              H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  SO.sub.2 (2-C.sub.6 H.sub.4 Br)                                                              H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  CH.sub.2 NO.sub.2                                                                            H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  CH(CH.sub.3)NO.sub.2                                                                         H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  C(CH.sub.3).sub.2 NO.sub.2                                                                   H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  C(CH.sub.3)(C.sub.6 H.sub.5)NO.sub.2                                                         H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  CH(C.sub.4 H.sub.9)NO.sub.2                                                                  H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  CH(4-C.sub.6 H.sub.4 Cl)NO.sub.2                                                             H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  CH(CN).sub.2  H     OCH.sub.3                                                                             OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            H     OC.sub.2 H.sub.5                                                                      CH.sub.3   N                                     H  N(CH.sub.3).sub.2                                                                            H     Cl     OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            H     F      OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            H     Br     OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            H     OCF.sub.2 H                                                                           CH.sub.3   CH                                    H  N(CH.sub.3).sub.2                                                                            H     CF.sub.2 H                                                                            CH.sub.3   CH                                    H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.2 CH.sub.2 F                                                                  CH.sub.3   CH                                    H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.2 CHF.sub.2                                                                   CH.sub.3   CH                                    H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.2 CF.sub.3                                                                    CH.sub.3   CH                                    H  N(CH.sub.3).sub.2                                                                            H     CF.sub.3                                                                              OCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                             H          CH                                    H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                        CH                                    H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                             NHCH.sub.3 N                                     H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                             N(OCH.sub.3)CH.sub.3                                                                      N                                     H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                             N(CH.sub.3).sub.2                                                                         N                                     H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                             CH.sub.2 CH.sub.3                                                                         CH                                    H  N(CH.sub.3).sub.2                                                                            H     CF.sub.3                                                                              CF.sub.3   CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              SCH.sub.3  CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              OCH.sub.2 CCH                                                                             CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              OCH.sub.2 CHCH.sub.2                                                                      CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              CH.sub.2 OCH.sub.2 CH.sub.3                                                               CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              OCH.sub.2 CH.sub.2 OCH.sub.3                                                              CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              CH.sub.2 SCH.sub.3                                                                        CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              CHO        CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              COCH.sub.3 CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              CH(OCH.sub.3).sub.2                                                                       CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                               ##STR18## CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              OCF.sub.2 H                                                                               CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              SCF.sub.2 H                                                                               CH                                    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              cyclopropyl                                                                               CH                                    __________________________________________________________________________

                                      TABLE II                                     __________________________________________________________________________     General Formula II                                                             Q  R R.sub.2                                                                          R.sub.4                                                                               R.sub.5 R.sub.6                                                                           R.sub.9                                                                               R.sub.12                                                                             R.sub.13                                                                              R.sub.14                                                                              X    m.p.                  __________________________________________________________________________                                                              (°C.)          Q-1                                                                               H H --     --      -- --     NHC.sub.6 H.sub.5                                                                    --     --     OCH.sub.3                  Q-1                                                                               H H --     --      -- --     CH.sub.3                                                                             --     --     OCH.sub.3                  Q-1                                                                               H H --     --      -- --     OCH.sub.3                                                                            --     --     OCH.sub.3                  Q-1                                                                               H H --     --      -- --     O-- .sub.-t-C.sub.4 H.sub.9                                                          --     --     OCH.sub.3                  Q-1                                                                               H H --     --      -- --     NHCH.sub.3                                                                           --     --     OCH.sub.3                  Q-2                                                                               H H --     --      -- CH.sub.3                                                                              CH.sub.3                                                                             --     --     OCH.sub.3                  Q-2                                                                               H H --     --      -- C.sub.6 H.sub.5                                                                       CH.sub.3                                                                             --     --     OCH.sub. 3                 Q-2                                                                               H H --     --      -- CH.sub.3                                                                              OCH.sub.3                                                                            --     --     OCH.sub.3                  Q-2                                                                               H H --     --      -- CH.sub.3                                                                              NHCH.sub.3                                                                           --     --     OCH.sub.3                  Q-2                                                                               H H --     --      -- CH.sub.3                                                                              NHC.sub.6 H.sub.5                                                                    --     --     OCH.sub.3                  Q-3                                                                               H H --     --      -- --     CH.sub.3                                                                             --     --     OCH.sub.3                  Q-3                                                                               H H --     --      -- --     OCH.sub.3                                                                            --     --     OCH.sub.3                  Q-3                                                                               H H --     --      -- --     O-- .sub.-t-C.sub.4 H.sub.9                                                          --     --     OCH.sub.3                  Q-3                                                                               H H --     --      -- --     NHCH.sub.3                                                                           --     --     OCH.sub.3                  Q-4                                                                               H H --     --      -- --     CH.sub.3                                                                             --     --     OCH.sub.3                  Q-4                                                                               H H --     --      -- --     OCH.sub.3                                                                            --     --     OCH.sub.3                  Q-4                                                                               H H --     --      -- --     O-- .sub.-t-C.sub. 4 H.sub.9                                                         --     --     OCH.sub.3                  Q-4                                                                               H H --     --      -- --     NHCH.sub.3                                                                           --     --     OCH.sub.3                  Q-5                                                                               H H --     --      -- --     --    --     --     OCH.sub.3                  Q-6                                                                               H H --     --      -- --     --    --     --     OCH.sub.3                  Q-7                                                                               H H --     --      -- --     --    --     --     OCH.sub.3                  Q-8                                                                               H H --     --      -- --     --    H      H      OCH.sub.3                  Q-8                                                                               H H --     --      -- --     --    H      4-CH.sub.3                                                                            OCH.sub.3                  Q-8                                                                               H H --     --      -- --     --    H      4-OCH.sub.3                                                                           OCH.sub.3                  Q-8                                                                               H H --     --      -- --     --    H      3-SCH.sub.3                                                                           OCH.sub.3                  Q-8                                                                               H H --     --      -- --     --    3-Cl   4-Cl   OCH.sub.3                  Q-8                                                                               H H --     --      -- --     --    H      4-CO.sub.2 CH.sub.3                                                                   OCH.sub.3                  Q-8                                                                               H H --     --      -- --     --    2-OCH.sub.3                                                                           5-OCH.sub.3                                                                           OCH.sub.3                  Q-8                                                                               H H --     --      -- --     --    2-F    5-NHCOCH.sub.3                                                                        OCH.sub.3                  Q-9                                                                               H H CH.sub.3                                                                              CH.sub.3                                                                               -- --     --    H      H      CH.sub.3                                                                            210-211               Q-9                                                                               H H CH.sub.3                                                                              CH.sub.3                                                                               -- --     --    2-NHCOCH.sub.3                                                                        H      OCH.sub.3                  Q-9                                                                               H H CH.sub.3                                                                              CH.sub.3                                                                               -- --     --    2-Cl   H      OCH.sub.3                  Q-9                                                                               H H CH.sub.3                                                                              CH.sub.3                                                                               -- --     --    2-OCH.sub.3                                                                           H      OCH.sub.3                  Q-9                                                                               H H CH.sub.3                                                                              CH.sub.3                                                                               -- --     --    2-SCH.sub.3                                                                           H      OCH.sub.3                  Q-9                                                                               H H C.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                        -- --     --    H      H      OCH.sub.3                  Q-9                                                                               H H CH.sub.3                                                                              CH.sub.2 CH═CH.sub.2                                                               -- --     --    H      H      OCH.sub.3                  Q-9                                                                               H H CH.sub.2 CH.sub.2 Cl                                                                  CH.sub.2 CH.sub.2 Cl                                                                   -- --     --    H      H      OCH.sub.3                  Q-9                                                                               H H CH.sub.2 CH.sub.2 OH                                                                  CH.sub.2 CH.sub.2 OH                                                                   -- --     --    H      H      OCH.sub.3                  Q-9                                                                               H H --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                     -- --     --    H      H      OCH.sub.3                  Q-10                                                                              H H --     --      -- --     --    H      H      OCH.sub.3                  Q-10                                                                              H H --     --      -- --     --    2-NHCOCH.sub.3                                                                        H      OCH.sub.3                  Q-10                                                                              H H --     --      -- --     --    2-Cl   H      OCH.sub.3                  Q-10                                                                              H H --     --      -- --     --    2-OCH.sub.3                                                                           H      OCH.sub.3                  Q-10                                                                              H H --     --      -- --     --    2-SCH.sub.3                                                                           H      OCH.sub.3                  Q-10                                                                              H H --     --      -- --     --    3-CO.sub.2 CH.sub.3                                                                   H      OCH.sub.3                  Q-10                                                                              H H --     --      -- --     --    3-Cl   5-Cl   OCH.sub.3                  Q-11                                                                              H H CH.sub.3                                                                              CH.sub.3                                                                               -- --     --    H      H      OCH.sub.3                  Q-11                                                                              H H CH.sub.3                                                                              CH.sub. 3                                                                              -- --     --    4-NHCOCH.sub.3                                                                        H      OCH.sub.3                  Q-11                                                                              H H CH.sub.3                                                                              CH.sub.3                                                                               -- --     --    4-Cl   H      OCH.sub.3                  Q-11                                                                              H H CH.sub.3                                                                              CH.sub.3                                                                               -- --     --    4-OCH.sub.3                                                                           H      OCH.sub.3                  Q-11                                                                              H H CH.sub.3                                                                              CH.sub.3                                                                               -- --     --    4-SCH.sub.3                                                                           H      OCH.sub.3                  Q-11                                                                              H H C.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                        -- --     --    H      H      OCH.sub.3                  Q-11                                                                              H H CH.sub.3                                                                              CH.sub.2 CH═CH.sub.2                                                               -- --     --    H      H      OCH.sub.3                  Q-11                                                                              H H CH.sub.2 CH.sub.2 Cl                                                                  CH.sub.2 CH.sub.2 Cl                                                                   -- --     --    H      H      OCH.sub.3                  Q-11                                                                              H H CH.sub.2 CH.sub.2 OH                                                                  CH.sub. CH.sub.2 OH                                                                    -- --     --    H      H      OCH.sub.3                  Q-11                                                                              H H --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                     -- --     --    H      H      OCH.sub.3                  Q-12                                                                              H H --     --      -- --     --    H      H      OCH.sub.3                  Q-12                                                                              H H --     --      -- --     --    4-NHCOCH.sub.3                                                                        H      OCH.sub.3                  Q-12                                                                              H H --     --      -- --     --    4-Cl   H      OCH.sub.3                  Q-12                                                                              H H --     --      -- --     --    4-OCH.sub.3                                                                           H      OCH.sub.3                  Q-12                                                                              H H --     --      -- --     --    4-SCH.sub.3                                                                           H      OCH.sub.3                  Q-12                                                                              H H --     --      -- --     --    4-CO.sub.2 CH.sub.3                                                                   H      OCH.sub.3                  Q-12                                                                              H H --     --      -- --     --    3-Cl   5-Cl   OCH.sub.3                  Q-13                                                                              H H --     --      CH.sub.3                                                                          H      --    --     --     OCH.sub.3                  Q-13                                                                              H H --     --      C.sub.4 H.sub.9                                                                   CH.sub.3                                                                              --    --     --     OCH.sub.3                  Q-13                                                                              H H --     --      CH.sub.3                                                                          C.sub.6 H.sub.5                                                                       --    --     --     OCH.sub.3                  Q-13                                                                              H H --     --      CH.sub.3                                                                          4-C.sub.6 H.sub.4 Cl                                                                  --    --     --     OCH.sub.3                  Q-13                                                                              H H --     --      CH.sub.3                                                                          2,4-C.sub.6 H.sub.3 Cl.sub.2                                                          --    --     --     OCH.sub.3                  Q-13                                                                              H H --     --      CH.sub.3                                                                          CH.sub.3                                                                              --    --     --     OCH.sub.3                  Q-14                                                                              H H --     --      -- CH.sub.3                                                                              --    H      --     OCH.sub.3                  Q-14                                                                              H H --     --      -- C.sub.6 H.sub.5                                                                       --    H      --     OCH.sub.3                  Q-14                                                                              H H --     --      -- 4-C.sub.6 H.sub.4 Cl                                                                  --    H      --     OCH.sub.3                  Q-14                                                                              H H --     --      -- CH.sub.3                                                                              --    CH.sub.3                                                                              --     OCH.sub.3                  Q-14                                                                              H H --     --      -- CH.sub.3                                                                              --    Cl     --     OCH.sub.3                  Q-14                                                                              H H --     --      -- CH.sub.3                                                                              --    OCH.sub.3                                                                             --     OCH.sub.3                  __________________________________________________________________________

                                      TABLE III                                    __________________________________________________________________________     General Formula III                                                            R  R.sub.1       R.sub.3     X      Y         Z  m.p. (°C.)             __________________________________________________________________________     CH.sub.3                                                                          N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            NO.sub.2    CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                             CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CF.sub.3    CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CF.sub.3    OCH.sub. 3                                                                            OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CF.sub.3    CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CF.sub.3    OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub. 3                                                                               CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 Cl                                                                      OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 Cl                                                                      CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                       CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                       OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                       CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                       OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.3    CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.3    OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.3    CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.3    OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Cl          CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Cl          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Cl          CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Cl          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Br          CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Br          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Br          CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Br          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            F           CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3 ).sub.2                                                                           F           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            F           CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            F           OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            H           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            H           CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                             -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.3                                                                 OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 .sub.-i-C.sub.3 H.sub.7                                                           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2CH.sub.2 CHCH.sub.2                                                                OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.2 Cl                                                              OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.2 OCH.sub.3                                                       OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OC.sub.4 H.sub.9                                                                           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SC.sub.4 H.sub.9                                                                           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub. 2 N(C.sub.2 H.sub.5).sub.2                                                         OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.2 CH.sub.3                                                                 OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 C.sub.4 H.sub.9                                                                   OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 Br                                                    OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 C.sub.4 H.sub.9                                                                  OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(C.sub.2 H.sub.5).sub.2                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 CF.sub.3                                                                 CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.2 CH.sub.2 Cl).sub.2                                                                CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 CH.sub.2 Br                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 CHCH.sub.2                                                               CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                                   ##STR19##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(OH)CH.sub.3 CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(OCH.sub.3)CH.sub.3                                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 OCH.sub.3                                                                CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)(cyclopropyl)                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)(cyclopentyl)                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR20##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR21##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR22##    CO.sub.2 CH.sub. 3                                                                         OCH.sub. 3                                                                            OCH.sub. 3                                                                               CH                               H  N(CH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                       CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.3).sub.2                                                CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3 )OC.sub.4 H.sub.9                                                                 CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  NHCN          CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR23##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.3 CH                               H  P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(CH.sub.2 CF.sub.3)OCH.sub.3                                                             CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub.3)CH.sub.2 CHCH.sub.2                                                           CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(CH.sub.3)SCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(CH.sub.3)NHCH.sub.3                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR24##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub. 3)CH.sub.2 CH.sub.2 OCH.sub.3                                                  CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub.3)cyclopropyl                                                                   CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P.sup.+ ( -n-C.sub.4 H.sub.9).sub.3                                                          CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P.sup.+ (CH.sub.3)(C.sub.2 H.sub.5).sub.2                                                    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SCH.sub.3     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S -n-C.sub.4 H.sub.9                                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SC.sub.6 H.sub.5                                                                             CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S(3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S(4-C.sub.6 H.sub.4 Cl)                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S(2-C.sub.6 H.sub.4 Br)                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 -n-C.sub.4 H.sub.9                                                                  CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 C.sub.6 H.sub.5                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 (3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 (4-C.sub.6 H.sub.4 Cl)                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 (2-C.sub.6 H.sub.4 Br)                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(CH.sub.3)NO.sub.2                                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  C(CH.sub.3).sub.2 NO.sub.2                                                                   CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  C(CH.sub.3)(C.sub.6 H.sub.5)NO.sub.2                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(C.sub.4 H.sub.9)NO.sub.2                                                                  CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(4-C.sub.6 H.sub.4 Cl)NO.sub.2                                                             CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(CN).sub.2  CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OC.sub.2 H.sub.5                                                                      CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          Cl     OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          F      OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          Br     OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCF.sub.2 H                                                                           CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CF.sub.2 H                                                                            CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.2 CH.sub.2 F                                                                  CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.2 CHF.sub.2                                                                   CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                    CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CF.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             H         CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                       CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             NHCH.sub.3                                                                               N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             N(CH.sub.3)OCH.sub.                                                                      N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             N(CH.sub.3).sub.2                                                                        N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.2 CH.sub.3                                                                        CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CF.sub.3                                                                              CF.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              SCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.2 CCH                                                                            CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.2 CHCH.sub.2                                                                     CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH.sub.2 OCH.sub.2 CH.sub.3                                                              CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.2 CH.sub.2 OCH.sub.3                                                             CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.2 SCH.sub.3                                                                       CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CHO    CH                                         H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              COCH.sub.3                                                                               CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH(OCH.sub.3).sub.2                                                                      CH                               H  N(CH.sub. 3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                               ##STR25##                                                                               CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCF.sub.2 H                                                                              CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub. 3                                                                             SCF.sub.2 H                                                                              CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              cyclopropyl                                                                              CH                               __________________________________________________________________________

                                      TABLE IV                                     __________________________________________________________________________     General Formula IV                                                             Q  R  R.sub.2                                                                             R.sub.4                                                                               R.sub.5 R.sub.6                                                                            R.sub.9                                                                               R.sub.12                                                                             R.sub.13                                                                              R.sub.14                                                                              m.p. (°                                                                 C.)                   __________________________________________________________________________     Q-1                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHC.sub.6 H.sub.5                                                                    --     --                           Q-1                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     CH.sub.3                                                                             --     --                           Q-1                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     OCH.sub.3                                                                            --     --                           Q-1                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     O--.sub.-t-C.sub.4 H.sub.9                                                           --     --                           Q-1                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHCH.sub.3                                                                           --     --                           Q-2                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              CH.sub.3                                                                             --     --                           Q-2                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  C.sub.6 H.sub.5                                                                       CH.sub. 3                                                                            --     --                           Q-2                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              OCH.sub.3                                                                            --     --                           Q-2                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              NHCH.sub.3                                                                           --     --                           Q-2                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              NHC.sub.6 H.sub.5                                                                    --     --                           Q-3                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     CH.sub.3                                                                             --     --                           Q-3                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     OCH.sub.3                                                                            --     --                           Q-3                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                          --     --                           Q-3                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHCH.sub.3                                                                           --     --                           Q-4                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     CH.sub.3                                                                             --     --                           Q-4                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     OCH.sub.3                                                                            --     --                           Q-4                                                                               H  CO.sub.2 CH.sub. 3                                                                  --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                          --     --                           Q-4                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHCH.sub.3                                                                           --     --                           Q-5                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    --     --                           Q-6                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    --     --                           Q-7                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    --     --                           Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      H                            Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      4-CH.sub.3                   Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      4-OCH.sub.3                  Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      3-SCH.sub.3                  Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-Cl   4-Cl                         Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      4-CO.sub.2 CH.sub.3          Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-OCH.sub.3                                                                           5-OCH.sub.3                  Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-F    5-NHCOCH.sub.3               Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    H      H      221-231               Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-NHCOCH.sub.3                                                                        H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-Cl   H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-OCH.sub.3                                                                           H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-SCH.sub.3                                                                           H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   C.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                        --  --     --    H      H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.2 CH═CH.sub.2                                                               --  --     --    H      H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 Cl                                                                  CH.sub.2 CH.sub.2 Cl                                                                   --  --     --    H      H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 OH                                                                  CH.sub.2 CH.sub.2 OH                                                                   --  --     --    H      H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                     --  --     --    H      H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-NHCOCH.sub.3                                                                        H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-Cl   H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-OCH.sub.3                                                                           H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-SCH.sub.3                                                                           H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-CO.sub.2 CH.sub.3                                                                   H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-Cl   5-Cl                         Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    H      H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-NHCOCH.sub.3                                                                        H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-Cl   H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-OCH.sub.3                                                                           H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-SCH.sub.3                                                                           H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   C.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                        --  --     --    H      H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.2 CH═CH.sub.2                                                               --  --     --    H      H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 Cl                                                                  CH.sub.2 CH.sub.2 Cl                                                                   --  --     --    H      H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 OH                                                                  CH.sub.2 CH.sub.2 OH                                                                   --  --     --    H      H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                     --  --     --    H      H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-NHCOCH.sub.3                                                                        H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-Cl   H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-OCH.sub.3                                                                           H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-SCH.sub.3                                                                           H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-CO.sub.2 CH.sub.3                                                                   H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-Cl   5-Cl                         Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           H      --    --     --                           Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      C.sub.4 H.sub.9                                                                    CH.sub.3                                                                              --    --     --                           Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           C.sub.6 H.sub.5                                                                       --    --     --                           Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           4-C.sub.6 H.sub.4 Cl                                                                  --    --     --                           Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           2,4-C.sub.6 H.sub.3 Cl.sub.2                                                          --    --     --                           Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           CH.sub.3                                                                              --    --     --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              --    H      --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  C.sub.6 H.sub.5                                                                       --    H      --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  4-C.sub.6 H.sub.4 Cl                                                                  --    H      --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              --    CH.sub.3                                                                              --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              --    Cl     --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              --    OCH.sub.3                                                                             --                           __________________________________________________________________________

                                      TABLE V                                      __________________________________________________________________________     General Formula V                                                              R  R.sub.1       R.sub.3     X      Y         Z  m.p. (°C.)             __________________________________________________________________________     CH.sub.3                                                                          N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            NO.sub.2    CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                             CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CF.sub.3    CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CF.sub.3    OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CF.sub.3    CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CF.sub.3    OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 Cl                                                                      OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 Cl                                                                      CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub. 2                                                                      CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                       OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                       CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                       OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.3    CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.3    OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.3    CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.3    OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Cl          CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Cl          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Cl          CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Cl          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Br          CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Br          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Br          CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Br          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            F           CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub. 3).sub.2                                                                           F           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            F           CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            F           OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            H           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            H           CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                             -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.3                                                                 OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2  .sub.-i-C.sub.3 H.sub.7                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CHCH.sub.2                                                               OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.2 Cl                                                              OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.2 OCH.sub.3                                                       OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OC.sub.4 H.sub.9                                                                           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SC.sub.4 H.sub.9                                                                           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3 ).sub.2                                                                           SO.sub.2 N(C.sub.2 H.sub.5).sub.2                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.2 CH.sub.3                                                                 OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 C.sub.4 H.sub.9                                                                   OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 Br                                                    OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 C.sub.4 H.sub.9                                                                  OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(C.sub.2 H.sub.5).sub.2                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 CF.sub.3                                                                 CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.2 CH.sub.2 Cl).sub.2                                                                CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 CH.sub.2 Br                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 CHCH.sub.2                                                               CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                                   ##STR26##    CO.sub.2 CH.sub.3                                                                          OCH.sub. 3                                                                            OCH.sub.3 CH                               H  N(OH)CH.sub.3 CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(OCH.sub.3)CH.sub.3                                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 OCH.sub.3                                                                CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)(cyclopropyl)                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)(cyclopentyl)                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR27##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR28##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR29##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                       CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.3).sub.2                                                CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)OC.sub.4 H.sub. 9                                                                 CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  NHCN          CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR30##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.3 CH                               H  P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(CH.sub.2 CF.sub.3)OCH.sub.3                                                             CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub.3)CH.sub.2 CHCH.sub.2                                                           CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(CH.sub.3)SCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(CH.sub.3)NHCH.sub.3                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR31##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                   CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub.3)cyclopropyl                                                                   CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P.sup.+ ( -n-C.sub.4 H.sub.9).sub.3                                                          CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P.sup.+ (CH.sub.3)(C.sub.2 H.sub.5).sub.2                                                    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SCH.sub.3     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S -n-C.sub.4 H.sub.9                                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SC.sub.6 H.sub.5                                                                             CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S(3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S(4-C.sub.6 H.sub.4 Cl)                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S(2-C.sub.6 H.sub.4 Br)                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub. 2 -n-C.sub.4 H.sub.9                                                                 CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 C.sub.6 H.sub.5                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 (3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 (4-C.sub.6 H.sub.4 Cl)                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 (2-C.sub.6 H.sub.4 Br)                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(CH.sub.3)NO.sub.2                                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  C(CH.sub.3).sub.2 NO.sub.2                                                                   CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  C(CH.sub.3)(C.sub.6 H.sub.5)NO.sub.2                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(C.sub.4 H.sub.9)NO.sub.2                                                                  CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(4-C.sub.6 H.sub.4 Cl)NO.sub.2                                                             CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(CN).sub.2  CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OC.sub.2 H.sub.5                                                                      CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          Cl     OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          F      OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          Br     OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCF.sub.2 H                                                                           CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CF.sub.2 H                                                                            CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.2 CH.sub.2 F                                                                  CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.2 CHF.sub.2                                                                   CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                    CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CF.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             H         CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                       CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             NHCH.sub.3                                                                               N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             N(CH.sub.3)OCH.sub.3                                                                     N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             N(CH.sub.3).sub.2                                                                        N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.2 CH.sub.3                                                                        CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CF.sub.3                                                                              CF.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              SCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.2 CCH                                                                            CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.2 CHCH.sub.2                                                                     CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH.sub.2 OCH.sub.2 CH.sub.3                                                              CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.2 CH.sub.2 OCH.sub.3                                                             CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.2 SCH.sub.3                                                                       CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CHO       CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              COCH.sub.3                                                                               CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH(OCH.sub.3).sub.2                                                                      CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                               ##STR32##                                                                               CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCF.sub.2 H                                                                              CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              SCF.sub.2 H                                                                              CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              cyclopropyl                                                                              CH                               __________________________________________________________________________

                                      TABLE VI                                     __________________________________________________________________________     General Formula VI                                                             Q  R  R.sub.2                                                                             R.sub.4                                                                               R.sub.5 R.sub.6                                                                            R.sub.9                                                                               R.sub.12                                                                             R.sub.13                                                                              R.sub.14                                                                              m.p.                  __________________________________________________________________________                                                              (°C.)          Q-1                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHC.sub.6 H.sub.5                                                                    --     --                           Q-1                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     CH.sub.3                                                                             --     --                           Q-1                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     OCH.sub.3                                                                            --     --                           Q-1                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                          --     --                           Q-1                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHCH.sub.3                                                                           --     --                           Q-2                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              CH.sub.3                                                                             --     --                           Q-2                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  C.sub.6 H.sub.5                                                                       CH.sub. 3                                                                            --     --                           Q-2                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              OCH.sub.3                                                                            --     --                           Q-2                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              NHCH.sub.3                                                                           --     --                           Q-2                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              NHC.sub.6 H.sub.5                                                                    --     --                           Q-3                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     CH.sub.3                                                                             --     --                           Q-3                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     OCH.sub.3                                                                            --     --                           Q-3                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                          --     --                           Q-3                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHCH.sub.3                                                                           --     --                           Q-4                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     CH.sub.3                                                                             --     --                           Q-4                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     OCH.sub.3                                                                            --     --                           Q-4                                                                               H  CO.sub.2 CH.sub. 3                                                                  --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                          --     --                           Q-4                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHCH.sub.3                                                                           --     --                           Q-5                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    --     --                           Q-6                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    --     --                           Q-7                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    --     --                           Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      H                            Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      4-CH.sub.3                   Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      4-OCH.sub.3                  Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      3-SCH.sub.3                  Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-Cl   4-Cl                         Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      4-CO.sub.2 CH.sub.3          Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-OCH.sub.3                                                                           5-OCH.sub.3                  Q-8                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-F    5-NHCOCH.sub.3               Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    H      H      221-231               Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-NHCOCH.sub.3                                                                        H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-Cl   H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-OCH.sub.3                                                                           H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-SCH.sub.3                                                                           H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   C.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                        --  --     --    H      H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.2 CH═CH.sub.2                                                               --  --     --    H      H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 Cl                                                                  CH.sub.2 CH.sub.2 Cl                                                                   --  --     --    H      H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 OH                                                                  CH.sub.2 CH.sub.2 OH                                                                   --  --     --    H      H                            Q-9                                                                               H  CO.sub.2 CH.sub.3                                                                   --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2--                                                      --  --     --    H      H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-NHCOCH.sub.3                                                                        H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-Cl   H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-OCH.sub.3                                                                           H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-SCH.sub.3                                                                           H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-CO.sub.2 CH.sub.3                                                                   H                            Q-10                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-Cl   5-Cl                         Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    H      H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-NHCOCH.sub.3                                                                        H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-Cl   H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-OCH.sub.3                                                                           H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-SCH.sub.3                                                                           H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   C.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                        --  --     --    H      H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.2 CH═CH.sub.2                                                               --  --     --    H      H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 Cl                                                                  CH.sub.2 CH.sub.2 Cl                                                                   --  --     --    H      H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 OH                                                                  CH.sub.2 CH.sub.2 OH                                                                   --  --     --    H      H                            Q-11                                                                              H  CO.sub.2 CH.sub.3                                                                   --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2--                                                      --  --     --    H      H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-NHCOCH.sub.3                                                                        H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-Cl   H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-OCH.sub.3                                                                           H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-SCH.sub.3                                                                           H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-CO.sub.2 CH.sub.3                                                                   H                            Q-12                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-Cl   5-Cl                         Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           H      --    --     --                           Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      C.sub.4 H.sub.9                                                                    CH.sub.3                                                                              --    --     --                           Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           C.sub.6 H.sub.5                                                                       --    --     --                           Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           4-C.sub.6 H.sub.4 Cl                                                                  --    --     --                           Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           2,4-C.sub.6 H.sub.3 Cl.sub.2                                                          --    --     --                           Q-13                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           CH.sub.3                                                                              --    --     --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              --    H      --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  C.sub.6 H.sub.5                                                                       --    H      --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  4-C.sub.6 H.sub.4 Cl                                                                  --    H      --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              --    CH.sub.3                                                                              --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub. 3                                                                             --    Cl     --                           Q-14                                                                              H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              --    OCH.sub.3                                                                             --                           __________________________________________________________________________

                                      TABLE VII                                    __________________________________________________________________________     General Formula VII                                                            R  R.sub.1       R.sub.3     X      Y         Z  m.p. (°C.)             __________________________________________________________________________     CH.sub.3                                                                          N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            NO.sub.2    CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                             CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CF.sub.3    CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CF.sub.3    OCH.sub. 3                                                                            OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CF.sub.3    CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CF.sub.3    OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub. 3                                                                               CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 Cl                                                                      OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 Cl                                                                      CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                       CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                       OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                       CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                       OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.3    CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.3    OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CH.sub.3    CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            CH.sub.3    OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Cl          CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Cl          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Cl          CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Cl          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Br          CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Br          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            Br          CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            Br          OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            F           CH.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3 ).sub.2                                                                           F           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            F           CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            F           OCH.sub.3                                                                             OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                            H           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            H           CH.sub.3                                                                              OCH.sub.3 N                                H  N(CH.sub.3).sub.2                                                                             -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.3                                                                 OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 .sub.-i-C.sub.3 H.sub.7                                                           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2CH.sub.2 CHCH.sub.2                                                                OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.2 Cl                                                              OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.2 OCH.sub.3                                                       OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OC.sub.4 H.sub.9                                                                           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SC.sub.4 H.sub.9                                                                           OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub. 2 N(C.sub.2 H.sub.5).sub.2                                                         OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.2 CH.sub.3                                                                 OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            SO.sub.2 C.sub.4 H.sub.9                                                                   OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 Br                                                    OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 C.sub.4 H.sub.9                                                                  OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(C.sub.2 H.sub.5).sub.2                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 CF.sub.3                                                                 CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.2 CH.sub.2 Cl).sub.2                                                                CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 CH.sub.2 Br                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 CHCH.sub.2                                                               CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                                   ##STR33##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(OH)CH.sub.3 CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(OCH.sub.3)CH.sub.3                                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 OCH.sub.3                                                                CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)(cyclopropyl)                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)(cyclopentyl)                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR34##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR35##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR36##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                       CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.3).sub.2                                                CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3)OC.sub.4 H.sub.9                                                                  CO.sub. 2 CH.sub.3                                                                         OCH.sub.3                                                                             OCH.sub.3 CH                               H  NHCN          CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR37##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.3 CH                               H  P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(CH.sub.2 CF.sub.3)OCH.sub.3                                                             CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub.3)CH.sub.2 CHCH.sub.2                                                           CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(CH.sub.3)SCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(CH.sub.3)NHCH.sub.3                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H                                                                                  ##STR38##    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                   CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P(O)(OCH.sub.3)cyclopropyl                                                                   CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P.sup.+ ( -n-C.sub.4 H.sub.9).sub.3                                                          CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  P.sup.+ (CH.sub.3)(C.sub.2 H.sub.5).sub.2                                                    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SCH.sub.3     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S -n-C.sub.4 H.sub.9                                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SC.sub.6 H.sub.5                                                                             CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S(3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S(4-C.sub.6 H.sub.4 Cl)                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  S(2-C.sub.6 H.sub.4 Br)                                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2  -n-C.sub.4 H.sub.9                                                                 CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 C.sub.6 H.sub.5                                                                     CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 (3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                      CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 (4-C.sub.6 H.sub.4 Cl)                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  SO.sub.2 (2-C.sub.6 H.sub.4 Br)                                                              CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(CH.sub.3)NO.sub.2                                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  C(CH.sub.3).sub.2 NO.sub.2                                                                   CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  C(CH.sub.3)(C.sub.6 H.sub.5)NO.sub.2                                                         CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(C.sub.4 H.sub.9)NO.sub.2                                                                  CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(4-C.sub.6 H.sub.4 Cl)NO.sub.2                                                             CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  CH(CN).sub.2  CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OC.sub.2 H.sub.5                                                                      CH.sub.3  N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          Cl     OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          F      OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          Br     OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCF.sub.2 H                                                                           CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CF.sub.2 H                                                                            CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.2 CH.sub.2 F                                                                  CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.2 CHF.sub.2                                                                   CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                    CH.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CF.sub.3                                                                              OCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             H         CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                       CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             NHCH.sub.3                                                                               N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             N(CH.sub.3)OCH.sub.3                                                                     N                                H  N(CH.sub. 3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             N(CH.sub.3).sub.2                                                                        N                                H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.2 CH.sub.3                                                                        CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CF.sub.3                                                                              CF.sub.3  CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              SCH.sub.3 CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCHCH.sub.2                                                                              CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCH.sub.2 CHCH.sub.2                                                                     CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH.sub.2 OCH.sub.2 CH.sub.3                                                              CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             OCH.sub.2 CH.sub.2 OCH.sub.3                                                             CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.2 SCH.sub.3                                                                       CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CHO       CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              COCH.sub.3                                                                               CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              CH(OCH.sub.3).sub.2                                                                      CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                               ##STR39##                                                                               CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              OCF.sub.2 H                                                                              CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              SCF.sub.2 H                                                                              CH                               H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                              cyclopropyl                                                                              CH                               __________________________________________________________________________

                                      TABLE VIII                                   __________________________________________________________________________     General Formula VIII                                                                                                                     m.p.                 Q   R  R.sub.2                                                                             R.sub.4                                                                               R.sub.5 R.sub.6                                                                            R.sub.9                                                                               R.sub.12                                                                             R.sub.13                                                                              R.sub.14                                                                              (°C.)         __________________________________________________________________________     Q-1 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHC.sub.6 H.sub.5                                                                    --     --                          Q-1 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     CH.sub.3                                                                             --     --                          Q-1 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     OCH.sub.3                                                                            --     --                          Q-1 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                          --     --                          Q-1 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHCH.sub.3                                                                           --     --                          Q-2 H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              CH.sub.3                                                                             --     --                          Q-2 H  CO.sub.2 CH.sub.3                                                                   --     --      --  C.sub.6 H.sub.5                                                                       CH.sub.3                                                                             --     --                          Q-2 H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              OCH.sub.3                                                                            --     --                          Q-2 H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              NHCH.sub.3                                                                           --     --                          Q-2 H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              NHC.sub.6 H.sub.5                                                                    --     --                          Q-3 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     CH.sub.3                                                                             --     --                          Q-3 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     OCH.sub.3                                                                            --     --                          Q-3 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                          --     --                          Q-3 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHCH.sub.3                                                                           --     --                          Q-4 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     CH.sub.3                                                                             --     --                          Q-4 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     OCH.sub.3                                                                            --     --                          Q-4 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                          --     --                          Q-4 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     NHCH.sub.3                                                                           --     --                          Q-5 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    --     --                          Q-6 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    --     --                          Q-7 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    --     --                          Q-8 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      H                           Q-8 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      4-CH.sub.3                  Q-8 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      4-OCH.sub.3                 Q-8 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      4-SCH.sub.3                 Q-8 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-Cl   4-Cl                        Q-8 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      4-CO.sub.2 CH.sub.3         Q-8 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-OCH.sub.3                                                                           5-OCH.sub.3                 Q-8 H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-F    5-NHCOCH.sub.3              Q-9 H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    H      H      221-231              Q-9 H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-NHCOCH.sub.3                                                                        H                           Q-9 H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-Cl   H                           Q-9 H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-OCH.sub.3                                                                           H                           Q-9 H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    2-SCH.sub.3                                                                           H                           Q-9 H  CO.sub.2 CH.sub.3                                                                   C.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                        --  --     --    H      H                           Q-9 H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.2 CH═CH.sub.2                                                               --  --     --    H      H                           Q-9 H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 Cl                                                                  CH.sub.2 CH.sub.2 Cl                                                                   --  --     --    H      H                           Q-9 H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 OH                                                                  CH.sub.2 CH.sub.2 OH                                                                   --  --     --    H      H                           Q-9 H  CO.sub.2 CH.sub.3                                                                   --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                     --  --     --    H      H                           Q-10                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      H                           Q-10                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-NHCOCH.sub.3                                                                        H                           Q-10                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-Cl   H                           Q-10                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-OCH.sub.3                                                                           H                           Q-10                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    2-SCH.sub.3                                                                           H                           Q-10                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-CO.sub.2 CH.sub.3                                                                   H                           Q-10                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-Cl   5-Cl                        Q-11                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    H      H                           Q-11                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-NHCOCH.sub.3                                                                        H                           Q-11                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-Cl   H                           Q-11                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-OCH.sub.3                                                                           H                           Q-11                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.3                                                                               --  --     --    4-SCH.sub.3                                                                           H                           Q-11                                                                               H  CO.sub.2 CH.sub.3                                                                   C.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                        --  --     --    H      H                           Q-11                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                              CH.sub.2 CH═CH.sub.2                                                               --  --     --    H      H                           Q-11                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 Cl                                                                  CH.sub.2 CH.sub.2 Cl                                                                   --  --     --    H      H                           Q-11                                                                               H  CO.sub.2 CH.sub.3                                                                   CH.sub.2 CH.sub.2 OH                                                                  CH.sub.2 CH.sub. 2 OH                                                                  --  --     --    H      H                           Q-11                                                                               H  CO.sub.2 CH.sub.3                                                                   --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                     --  --     --    H      H                           Q-12                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    H      H                           Q-12                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-NHCOCH.sub.3                                                                        H                           Q-12                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-Cl   H                           Q-12                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-OCH.sub.3                                                                           H                           Q-12                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-SCH.sub.3                                                                           H                           Q-12                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    4-CO.sub.2 CH.sub.3                                                                   H                           Q-12                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  --     --    3-Cl   5-Cl                        Q-13                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           H      --    --     --                          Q-13                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      C.sub.4 H.sub.9                                                                    CH.sub.3                                                                              --    --     --                          Q-13                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           C.sub.6 H.sub.5                                                                       --    --     --                          Q-13                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           4-C.sub.6 H.sub.4 Cl                                                                  --    --     --                          Q-13                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           2,4-C.sub.6 H.sub.3 Cl.sub.                                                           --    --     --                          Q-13                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      CH.sub.3                                                                           CH.sub.3                                                                              --    --     --                          Q-14                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              --    H      --                          Q-14                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  C.sub.6 H.sub.5                                                                       --    H      --                          Q-14                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  4-C.sub.6 H.sub.4 Cl                                                                  --    H      --                          Q-14                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              --    CH.sub.3                                                                              --                          Q-14                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              --    Cl     --                          Q-14                                                                               H  CO.sub.2 CH.sub.3                                                                   --     --      --  CH.sub.3                                                                              --    OCH.sub.3                                                                             --                          __________________________________________________________________________

                  TABLE IX                                                         ______________________________________                                         General Formula IX                                                                                                       m.p.                                 R    R.sub.1        R.sub.2   X.sub.1                                                                               Y.sub.1                                                                             (°C.)                         ______________________________________                                         H    N(CH.sub.3).sub.2                                                                             H         CH.sub.3                                                                              O                                         H    N(CH.sub.3).sub.2                                                                             H         CH.sub.3                                                                              CH.sub.2                                  H    N(CH.sub.3).sub.2                                                                             H         OCH.sub.3                                                                             O                                         H    N(CH.sub.3).sub.2                                                                             H         OCH.sub.3                                                                             CH.sub.2                                  H    N(CH.sub.3).sub.2                                                                             H         OC.sub.2 H.sub.5                                                                      O                                         H    N(CH.sub.3).sub.2                                                                             H         OC.sub.2 H.sub.5                                                                      CH.sub.2                                  H    N(CH.sub.3).sub.2                                                                             H         OCF.sub.2 H                                                                           O                                         H    N(CH.sub.3).sub.2                                                                             H         OCF.sub.2 H                                                                           CH.sub.2                                  CH.sub.3                                                                            N(CH.sub.3).sub.2                                                                             H         OCH.sub.3                                                                             O                                         H    N(CH.sub.3).sub.2                                                                             6-Cl      CH.sub.3                                                                              O                                         H    N(CH.sub.3).sub.2                                                                             5-OCH.sub.3                                                                              CH.sub.3                                                                              O                                         H    N(CH.sub.3).sub.2                                                                             5-SCH.sub.3                                                                              CH.sub.3                                                                              O                                         H    N(CH.sub.3).sub.2                                                                             5-N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                              O                                         H    N(CH.sub.3).sub.2                                                                             5-NO.sub.2                                                                               CH.sub.3                                                                              O                                         H    N(CH.sub.3).sub.2                                                                             6-CH.sub.3                                                                               CH.sub.3                                                                              O                                         H    N(CH.sub.3).sub.2                                                                             6-CF.sub.3                                                                               CH.sub.3                                                                              O                                         H    N(CH.sub.3)C.sub.4 H.sub.9                                                                    H         CH.sub.3                                                                              O                                         H    N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                           H         CH.sub.3                                                                              O                                         H    N(OH)CH.sub.3  H         CH.sub.3                                                                              O                                         H    N(CH.sub.3)CH.sub.2 OH                                                                        H         CH.sub.3                                                                              O                                         H    NHCN           H         CH.sub.3                                                                              O                                         H    P(O)(OCH.sub.3).sub.2                                                                         H         CH.sub.3                                                                              O                                         H    P(O)(CH.sub.3)OCH.sub.3                                                                       H         CH.sub.3                                                                              O                                         H    P(S)(CH.sub.3)OCH.sub.3                                                                       H         CH.sub.3                                                                              O                                         H    p.sup.+ (C.sub.6 H.sub.5).sub.3                                                               H         CH.sub.3                                                                              O                                         H    SCH.sub.3      H         CH.sub.3                                                                              O                                         H    SO.sub.2 CH.sub.3                                                                             H         CH.sub.3                                                                              O                                         H    CH.sub.2 NO.sub.2                                                                             H         CH.sub.3                                                                              O                                         H    CH(CN).sub.2   H         CH.sub.3                                                                              O                                         ______________________________________                                    

                  TABLE X                                                          ______________________________________                                         General Formula X                                                                                                                m.p.                         Q    R R.sub.2                                                                             R.sub.4                                                                               R.sub.5                                                                             R.sub.6                                                                             R.sub.9                                                                              R.sub.12                                                                            R.sub.13                                                                            R.sub.14                                                                            (°C.)                 ______________________________________                                         Q-1  H H    --     --   --   --    OCH.sub.3                                                                           --   --                                Q-1  H H    --     --   --   --    CH.sub.3                                                                            --   --                                Q-2  H H    --     --   --   CH.sub.3                                                                             OCH.sub.3                                                                           --   --                                Q-2  H H    --     --   --   CH.sub.3                                                                             CH.sub.3                                                                            --   --                                Q-3  H H    --     --   --   --    OCH.sub.3                                                                           --   --                                Q-3  H H    --     --   --   --    CH.sub.3                                                                            --   --                                Q-4  H H    --     --   --   --    OCH.sub.3                                                                           --   --                                Q-4  H H    --     --   --   --    CH.sub.3                                                                            --   --                                Q-5  H H    --     --   --   --    --   --   --                                Q-6  H H    --     --   --   --    --   --   --                                Q-7  H H    --     --   --   --    --   --   --                                Q-8  H H    --     --   --   --    --   H    H                                 Q-9  H H    CH.sub.3                                                                              CH.sub.3                                                                            --   --    --   H    H                                 Q-10 H H    --     --   --   --    --   H    H                                 Q-11 H H    CH.sub.3                                                                              CH.sub.3                                                                            --   --    --   CH.sub.3                                                                            H                                 Q-12 H H    --     --   --   --    --   CH.sub.3                                                                            H                                 Q-13 H H    --     --   CH.sub.3                                                                            CH.sub.3                                                                             --   --   --                                Q-14 H H    --     --   CH.sub.3                                                                            CH.sub.3                                                                             --   --   --                                ______________________________________                                    

                  TABLE XI                                                         ______________________________________                                         General Formula XI                                                                                                       m.p.                                 R   R.sub.1         R.sub.2      X.sub.1                                                                             Y.sub.1                                                                            (°C.)                         ______________________________________                                         H   N(CH.sub.3).sub.2                                                                              CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              NO.sub.2     CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              CF.sub.3     CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              OCH.sub.3    CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              SCH.sub.3    CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                                  CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              SO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              OSO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              OCH.sub.2 CH═CH.sub.2                                                                   CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              CH.sub.3     CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              Cl           CH.sub.3                                                                            O                                        H   N(CH.sub.3)C.sub.4 H.sub.9                                                                     CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                            CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(OH)CH.sub.3   CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3)CH.sub.2 OH                                                                         CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   NHCN            CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P(O)(OCH.sub.3).sub.2                                                                          CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P(O)(CH.sub.3)OCH.sub.3                                                                        CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P(S)(CH.sub.3)OCH.sub.3                                                                        CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                                CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   SCH.sub.3       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   SO.sub.2 CH.sub.3                                                                              CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   CH.sub.2 NO.sub.2                                                                              CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   CH(CN).sub.2    CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        ______________________________________                                    

                  TABLE XII                                                        ______________________________________                                         General Formula XII                                                                                                      m.p.                                 Q    RR.sub.3  R.sub.4 R.sub.5                                                                         R.sub.6 R.sub.9                                                                       R.sub.12                                                                             R.sub.13                                                                            R.sub.14 (°C.)                ______________________________________                                         Q-1  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-1  HCO.sub.2 CH.sub.3                                                                       ----     ----   CH.sub.3                                                                             --   --                                   Q-2  HCO.sub.2 CH.sub.3                                                                       ----     --CH.sub.3                                                                            OCH.sub.3                                                                            --   --                                   Q-2  HCO.sub.2 CH.sub.3                                                                       ----     --CH.sub.3                                                                            CH.sub.3                                                                             --   --                                   Q-3  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-3  HCO.sub.2 CH.sub.3                                                                       ----     ----   CH.sub.3                                                                             --   --                                   Q-4  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-4  HCO.sub.2 CH.sub.3                                                                       -- --    ----   CH.sub.3                                                                             --   --                                   Q-5  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-6  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-7  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-8  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    H    H                                    Q-9  HCO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3                                                                       ----   --    H    H                                    Q-10 HCO.sub.2 CH.sub.3                                                                       ----     ----   --    H    H                                    Q-11 HCO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3                                                                       ----   --    CH.sub.3                                                                            H                                    Q-12 HCO.sub.2 CH.sub.3                                                                       ----     ----   --    CH.sub.3                                                                            H                                    Q-13 HCO.sub.2 CH.sub.3                                                                       ----     CH.sub.3 CH.sub.3                                                                     --    --   --                                   Q-14 HCO.sub.2 CH.sub.3                                                                       ----     CH.sub.3  CH.sub.3                                                                    --    --   --                                   ______________________________________                                    

                  TABLE XIII                                                       ______________________________________                                         General Formula XIII                                                                                                     m.p.                                 R   R.sub.1         R.sub.2      X.sub.1                                                                             Y.sub.1                                                                            (°C.)                         ______________________________________                                         H   N(CH.sub.3).sub.2                                                                              CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              NO.sub.2     CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              CF.sub.3     CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              OCH.sub.3    CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              SCH.sub.3    CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                                  CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              SO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              OSO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              OCH.sub.2 CH═CH.sub.2                                                                   CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              CH.sub.3     CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              Cl           CH.sub.3                                                                            O                                        H   N(CH.sub.3)C.sub.4 H.sub.9                                                                     CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                            CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(OH)CH.sub.3   CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3)CH.sub.2 OH                                                                         CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   NHCN            CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P(O)(OCH.sub.3).sub.2                                                                          CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P(O)(CH.sub.3)OCH.sub.3                                                                        CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P(S)(CH.sub.3)OCH.sub.3                                                                        CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                                CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   SCH.sub.3       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   SO.sub.2 CH.sub.3                                                                              CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   CH.sub.2 NO.sub.2                                                                              CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   CH(CN).sub.2    CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        ______________________________________                                    

                  TABLE XIV                                                        ______________________________________                                         General Formula XIV                                                                                                      m.p.                                 Q    RR.sub.3  R.sub.4 R.sub.5                                                                         R.sub.6 R.sub.9                                                                       R.sub.12                                                                             R.sub.13                                                                            R.sub.14 (°C.)                ______________________________________                                         Q-1  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-1  HCO.sub.2 CH.sub.3                                                                       ----     ----   CH.sub.3                                                                             --   --                                   Q-2  HCO.sub.2 CH.sub.3                                                                       ----     --CH.sub.3                                                                            OCH.sub.3                                                                            --   --                                   Q-2  HCO.sub.2 CH.sub.3                                                                       ----     --CH.sub.3                                                                            CH.sub.3                                                                             --   --                                   Q-3  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-3  HCO.sub.2 CH.sub.3                                                                       ----     ----   CH.sub.3                                                                             --   --                                   Q-4  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-4  HCO.sub.2 CH.sub.3                                                                       -- --    ----   CH.sub.3                                                                             --   --                                   Q-5  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-6  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-7  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-8  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    H    H                                    Q-9  HCO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3                                                                       ----   --    H    H                                    Q-10 HCO.sub.2 CH.sub.3                                                                       ----     ----   --    H    H                                    Q-11 HCO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3                                                                       ----   --    CH.sub.3                                                                            H                                    Q-12 HCO.sub.2 CH.sub.3                                                                       ----     ----   --    CH.sub.3                                                                            H                                    Q-13 HCO.sub.2 CH.sub.3                                                                       ----     CH.sub.3 CH.sub.3                                                                     --    --   --                                   Q-14 HCO.sub.2 CH.sub.3                                                                       ----     CH.sub.3  CH.sub.3                                                                    --    --   --                                   ______________________________________                                    

                  TABLE XV                                                         ______________________________________                                         General Formula XV                                                                                                       m.p.                                 R   R.sub.1         R.sub.2      X.sub.1                                                                             Y.sub.1                                                                            (°C.)                         ______________________________________                                         H   N(CH.sub.3).sub.2                                                                              CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              NO.sub.2     CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              CF.sub.3     CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              OCH.sub.3    CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              SCH.sub.3    CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                                  CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              SO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              OSO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              OCH.sub.2 CH═CH.sub.2                                                                   CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              CH.sub.3     CH.sub.3                                                                            O                                        H   N(CH.sub.3).sub.2                                                                              Cl           CH.sub.3                                                                            O                                        H   N(CH.sub.3)C.sub.4 H.sub.9                                                                     CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                            CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(OH)CH.sub.3   CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   N(CH.sub.3)CH.sub.2 OH                                                                         CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   NHCN            CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P(O)(OCH.sub.3).sub.2                                                                          CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P(O)(CH.sub.3)OCH.sub.3                                                                        CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P(S)(CH.sub.3)OCH.sub.3                                                                        CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                                CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   SCH.sub.3       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   SO.sub.2 CH.sub.3                                                                              CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   CH.sub.2 NO.sub.2                                                                              CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        H   CH(CN).sub.2    CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            O                                        ______________________________________                                    

                  TABLE XVI                                                        ______________________________________                                         General Formula XVI                                                                                                      m.p.                                 Q    RR.sub.3  R.sub.4 R.sub.5                                                                         R.sub.6 R.sub.9                                                                       R.sub.12                                                                             R.sub.13                                                                            R.sub.14 (°C.)                ______________________________________                                         Q-1  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-1  HCO.sub.2 CH.sub.3                                                                       ----     ----   CH.sub.3                                                                             --   --                                   Q-2  HCO.sub.2 CH.sub.3                                                                       ----     --CH.sub.3                                                                            OCH.sub.3                                                                            --   --                                   Q-2  HCO.sub.2 CH.sub.3                                                                       ----     --CH.sub.3                                                                            CH.sub.3                                                                             --   --                                   Q-3  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-3  HCO.sub.2 CH.sub.3                                                                       ----     ----   CH.sub.3                                                                             --   --                                   Q-4  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-4  HCO.sub.2 CH.sub.3                                                                       -- --    ----   CH.sub.3                                                                             --   --                                   Q-5  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-6  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-7  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-8  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    H    H                                    Q-9  HCO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3                                                                       ----   --    H    H                                    Q-10 HCO.sub.2 CH.sub.3                                                                       ----     ----   --    H    H                                    Q-11 HCO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3                                                                       ----   --    CH.sub.3                                                                            H                                    Q-12 HCO.sub.2 CH.sub.3                                                                       ----     ----   --    CH.sub.3                                                                            H                                    Q-13 HCO.sub.2 CH.sub.3                                                                       ----     CH.sub.3 CH.sub.3                                                                     --    --   --                                   Q-14 HCO.sub.2 CH.sub.3                                                                       ----     CH.sub.3  CH.sub.3                                                                    --    --   --                                   ______________________________________                                    

                  TABLE XVII                                                       ______________________________________                                         General Formula XVII                                                                                                     m.p.                                 R    R.sub.1        R.sub.2   X.sub.1                                                                               Y.sub.2                                                                             (°C.)                         ______________________________________                                         H    N(CH.sub.3).sub.2                                                                             H         CH.sub.3                                                                              H                                         H    N(CH.sub.3).sub.2                                                                             H         CH.sub.3                                                                              CH.sub.3                                  H    N(CH.sub.3).sub.2                                                                             H         OCH.sub.3                                                                             H                                         H    N(CH.sub.3).sub.2                                                                             H         OCH.sub.3                                                                             CH.sub.3                                  H    N(CH.sub.3).sub.2                                                                             H         OC.sub.2 H.sub.5                                                                      H                                         H    N(CH.sub.3).sub.2                                                                             H         OC.sub.2 H.sub.5                                                                      CH.sub.3                                  H    N(CH.sub.3).sub.2                                                                             H         OCF.sub.2 H                                                                           H                                         H    N(CH.sub.3).sub.2                                                                             H         OCF.sub.2 H                                                                           CH.sub.3                                  CH.sub.3                                                                            N(CH.sub.3).sub.2                                                                             H         CH.sub.3                                                                              CH.sub.3                                  H    N(CH.sub.3).sub.2                                                                             6-Cl      CH.sub.3                                                                              CH.sub.3                                  H    N(CH.sub.3).sub.2                                                                             5-OCH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                  H    N(CH.sub.3).sub.2                                                                             5-SCH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                  H    N(CH.sub.3).sub.2                                                                             5-N(CH.sub.3).sub.2                                                                      CH.sub.3                                                                              CH.sub.3                                  H    N(CH.sub.3).sub.2                                                                             5-NO.sub.2                                                                               CH.sub.3                                                                              CH.sub.3                                  H    N(CH.sub.3).sub.2                                                                             6-CH.sub.3                                                                               CH.sub.3                                                                              CH.sub.3                                  H    N(CH.sub.3).sub.2                                                                             6-CF.sub.3                                                                               CH.sub.3                                                                              CH.sub.3                                  H    N(CH.sub.3)C.sub.4 H.sub.9                                                                    H         CH.sub.3                                                                              CH.sub.3                                  H    N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                           H         CH.sub.3                                                                              CH.sub.3                                  H    N(OH)CH.sub.3  H         CH.sub.3                                                                              CH.sub.3                                  H    N(CH.sub.3)CH.sub.2 OH                                                                        H         CH.sub.3                                                                              CH.sub.3                                  H    NHCN           H         CH.sub.3                                                                              CH.sub.3                                  H    P(O)(OCH.sub.3).sub.2                                                                         H         CH.sub.3                                                                              CH.sub.3                                  H    P(O)(CH.sub.3)OCH.sub.3                                                                       H         CH.sub.3                                                                              CH.sub.3                                  H    P(S)(CH.sub.3)OCH.sub.3                                                                       H         CH.sub.3                                                                              CH.sub.3                                  H    P.sup.+ (C.sub.6 H.sub.5).sub.3                                                               H         CH.sub.3                                                                              CH.sub.3                                  H    SCH.sub.3      H         CH.sub.3                                                                              CH.sub.3                                  H    SO.sub.2 CH.sub.3                                                                             H         CH.sub.3                                                                              CH.sub.3                                  H    CH.sub.2 NO.sub.2                                                                             H         CH.sub.3                                                                              CH.sub.3                                  H    CH(CN).sub.2   H         CH.sub.3                                                                              CH.sub.3                                  ______________________________________                                    

                  TABLE XVIII                                                      ______________________________________                                         General Formula XVIII                                                                                                          m.p.                           Q    R     R.sub.2                                                                              R.sub.4                                                                             R.sub.5                                                                             R.sub.6                                                                             R.sub.9                                                                             R.sub.12                                                                             R.sub.13                                                                            R.sub.14(°C.)           ______________________________________                                         Q-1  H     H     --   --   --   --   OCH.sub.3                                                                            --   --                             Q-1  H     H     --   --   --   --   CH.sub.3                                                                             --   --                             Q-2  H     H     --   --   --   CH.sub.3                                                                            OCH.sub.3                                                                            --   --                             Q-2  H     H     --   --   --   CH.sub.3                                                                            CH.sub.3                                                                             --   --                             Q-3  H     H     --   --   --   --   OCH.sub.3                                                                            --   --                             Q-3  H     H     --   --   --   --   CH.sub.3                                                                             --   --                             Q-4  H     H     --   --   --   --   OCH.sub.3                                                                            --   --                             Q-4  H     H     --   --   --   --   CH.sub.3                                                                             --   --                             Q-5  H     H     --   --   --   --   --    --   --                             Q-6  H     H     --   --   --   --   --    --   --                             Q-7  H     H     --   --   --   --   --    --   --                             Q-8  H     H     --   --   --   --   --    H    H                              Q-9  H     H     CH.sub.3                                                                            CH.sub.3                                                                            --   --   --    H    H                              Q-10 H     H     --   --   --   --   --    H    H                              Q-11 H     H     CH.sub.3                                                                            CH.sub.3                                                                            --   --   --    CH.sub.3                                                                            H                              Q-12 H     H     --   --   --   --   --    CH.sub.3                                                                            H                              Q-13 H     H     --   --   CH.sub.3                                                                            CH.sub.3                                                                            --    --   --                             Q-14 H     H     --   --   CH.sub.3                                                                            CH.sub.3                                                                            --    --   --                             ______________________________________                                    

                  TABLE XIX                                                        ______________________________________                                         General Formula XIX                                                                                                      m.p.                                 R   R.sub.1        R.sub.2      X.sub.1                                                                             Y.sub.2                                                                             (°C.)                         ______________________________________                                         H   N(CH.sub.3).sub.2                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             NO.sub.2     CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             CF.sub.3     CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             OCH.sub.3    CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             SCH.sub.3    CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                                  CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             SO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             OSO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             OCH.sub.2 CH═CH.sub.2                                                                   CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             CH.sub.3     CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             Cl           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3)C.sub.4 H.sub.9                                                                    CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub. 3)CH.sub.2 CH═CH.sub.2                                                          CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3)CH.sub.2 OH                                                                        CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   NHCN           CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P(O)(OCH.sub.3).sub.2                                                                         CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P(O)(CH.sub.3)OCH.sub.3                                                                       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P(S)(CH.sub.3)OCH.sub.3                                                                       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                               CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   SO.sub.2 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   CH.sub.2 NO.sub.2                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  ______________________________________                                    

                  TABLE XX                                                         ______________________________________                                         General Formula XX                                                                                                       m.p.                                 Q    RR.sub.3  R.sub.4 R.sub.5                                                                         R.sub.6 R.sub.9                                                                       R.sub.12                                                                             R.sub.13                                                                            R.sub.14(°C.)                 ______________________________________                                         Q-1  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-1  HCO.sub.2 CH.sub.3                                                                       ----     ---    CH.sub.3                                                                             --   --                                   Q-2  HCO.sub.2 CH.sub.3                                                                       ----     --CH.sub.3                                                                            OCH.sub.3                                                                            --   --                                   Q-2  HCO.sub.2 CH.sub.3                                                                       ----     --CH.sub.3                                                                            CH.sub.3                                                                             --   --                                   Q-3  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-3  HCO.sub.2 CH.sub.3                                                                       ----     ----   CH.sub.3                                                                             --   --                                   Q-4  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-4  HCO.sub.2 CH.sub. 3                                                                      ----     ----   CH.sub.3                                                                             --   --                                   Q-5  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-6  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-7  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-8  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    H    H                                    Q-9  HCO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3                                                                       ----   --    H    H                                    Q-10 HCO.sub.2 CH.sub.3                                                                       ----     ----   --    H    H                                    Q-11 HCO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3                                                                       ----   --    CH.sub.3                                                                            H                                    Q-12 HCO.sub.2 CH.sub.3                                                                       ----     ----   --    CH.sub.3                                                                            H                                    Q-13 HCO.sub.2 CH.sub.3                                                                       ----     CH.sub.3 CH.sub.3                                                                     --    --   --                                   Q-14 HCO.sub.2 CH.sub.3                                                                       ----     CH.sub.3 CH.sub.3                                                                     --    --   --                                   ______________________________________                                    

                  TABLE XXI                                                        ______________________________________                                         General Formula XXI                                                                                                      m.p.                                 R   R.sub.1        R.sub.2      X.sub.1                                                                             Y.sub.2                                                                             (°C.)                         ______________________________________                                         H   N(CH.sub.3).sub.2                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             NO.sub.2     CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             CF.sub.3     CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             OCH.sub.3    CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             SCH.sub.3    CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                                  CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             SO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             OSO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             OCH.sub.2 CH═CH.sub.2                                                                   CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             CH.sub.3     CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             Cl           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3)C.sub.4 H.sub.9                                                                    CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub. 3)CH.sub.2 CH═CH.sub.2                                                          CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3)CH.sub.2 OH                                                                        CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   NHCN           CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P(O)(OCH.sub.3).sub.2                                                                         CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P(O)(CH.sub.3)OCH.sub.3                                                                       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P(S)(CH.sub.3)OCH.sub.3                                                                       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                               CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   SO.sub.2 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   CH.sub.2 NO.sub.2                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  ______________________________________                                    

                                      TABLE XXII                                   __________________________________________________________________________     General Formula XXII                                                           Q  R R.sub.3                                                                             R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.9                                                                           R.sub.12                                                                           R.sub.13                                                                          R.sub.14                                                                          m.p. (°C.)                              __________________________________________________________________________     Q-1                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- -- OCH.sub.3                                                                          -- --                                                Q-1                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- -- CH.sub.3                                                                           -- --                                                Q-2                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- CH.sub.3                                                                          OCH.sub.3                                                                          -- --                                                Q-2                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- CH.sub.3                                                                          CH.sub.3                                                                           -- --                                                Q-3                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- -- OCH.sub.3                                                                          -- --                                                Q-3                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- -- CH.sub.3                                                                           -- --                                                Q-4                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- -- OCH.sub.3                                                                          -- --                                                Q-4                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- -- CH.sub.3                                                                           -- --                                                Q-5                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- -- --  -- --                                                Q-6                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- -- --  -- --                                                Q-7                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- -- --  -- --                                                Q-8                                                                               H CO.sub.2 CH.sub.3                                                                   -- -- -- -- --  H  H                                                 Q-9                                                                               H CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                          CH.sub.3                                                                          -- -- --  H  H                                                 Q-10                                                                              H CO.sub.2 CH.sub.3                                                                   -- -- -- -- --  H  H                                                 Q-11                                                                              H CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                          CH.sub.3                                                                          -- -- --  CH.sub.3                                                                          H                                                 Q-12                                                                              H CO.sub.2 CH.sub.3                                                                   -- -- -- -- --  CH.sub.3                                                                          H                                                 Q-13                                                                              H CO.sub.2 CH.sub.3                                                                   -- -- CH.sub.3                                                                          CH.sub.3                                                                          --  -- --                                                Q-14                                                                              H CO.sub.2 CH.sub.3                                                                   -- -- CH.sub.3                                                                          CH.sub.3                                                                          --  -- --                                                __________________________________________________________________________

                  TABLE XXIII                                                      ______________________________________                                         General Formula XXIII                                                                                                    m.p.                                 R   R.sub.1        R.sub.2      X.sub.1                                                                             Y.sub.2                                                                             (°C.)                         ______________________________________                                         H   N(CH.sub.3).sub.2                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             NO.sub.2     CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             CF.sub.3     CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             OCH.sub.3    CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             SCH.sub.3    CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                                  CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             SO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             OSO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             OCH.sub.2 CH═CH.sub.2                                                                   CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             CH.sub.3     CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3).sub.2                                                                             Cl           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3)C.sub.4 H.sub.9                                                                    CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub. 3)CH.sub.2 CH═CH.sub.2                                                          CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   N(CH.sub.3)CH.sub.2 OH                                                                        CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   NHCN           CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P(O)(OCH.sub.3).sub.2                                                                         CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P(O)(CH.sub.3)OCH.sub.3                                                                       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P(S)(CH.sub.3)OCH.sub.3                                                                       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                               CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   SO.sub.2 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   CH.sub.2 NO.sub.2                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                  ______________________________________                                    

                  TABLE XXIV                                                       ______________________________________                                         General Formula XXIV                                                                                                   m.p.                                   Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                              R.sub.14            (°C.)                           ______________________________________                                         Q-1  H     CO.sub.2 CH.sub.3                                                                       --------OCH.sub.3 ----                                     Q-1  H     CO.sub.2 CH.sub.3                                                                       --------CH.sub.3 ----                                      Q-2  H     CO.sub.2 CH.sub.3                                                                       ------CH.sub.3 OCH.sub.3 ----                              Q-2  H     CO.sub.2 CH.sub.3                                                                       ------CH.sub.3 CH.sub.3 ----                               Q-3  H     CO.sub.2 CH.sub.3                                                                       --------OCH.sub.3 ----                                     Q-3  H     CO.sub.2 CH.sub.3                                                                       --------CH.sub.3 ----                                      Q-4  H     CO.sub.2 CH.sub.3                                                                       --------OCH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                       --------CH.sub.3 ----                                      Q-5  H     CO.sub.2 CH.sub.3                                                                       --------------                                             Q-6  H     CO.sub.2 CH.sub.3                                                                       --------------                                             Q-7  H     CO.sub.2 CH.sub.3                                                                       --------------                                             Q-8  H     CO.sub.2 CH.sub.3                                                                       ----------HH                                               Q-9  H     CO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3 ------HH                                 Q-10 H     CO.sub.2 CH.sub.3                                                                       ----------HH                                               Q-11 H     CO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3 ------CH.sub.3 H                         Q-12 H     CO.sub.2 CH.sub.3                                                                       ----------CH.sub.3 H                                       Q-13 H     CO.sub.2 CH.sub.3                                                                       ----CH.sub.3 CH.sub.3 ------                               Q-14 H     CO.sub.2 CH.sub.3                                                                       ----CH.sub.3 CH.sub.3 ------                               ______________________________________                                    

                  TABLE XXV                                                        ______________________________________                                         General Formula XXV                                                            R    R.sub.1        R.sub.2   X.sub.1                                                                               m.p. (°C.)                         ______________________________________                                         H    N(CH.sub.3).sub.2                                                                             H         CH.sub.3                                         H    N(CH.sub.3).sub.2                                                                             H         OCH.sub.3                                        H    N(CH.sub.3).sub.2                                                                             H         OC.sub.2 H.sub.5                                 H    N(CH.sub.3).sub.2                                                                             H         OCF.sub.2 H                                      CH.sub.3                                                                            N(CH.sub.3).sub.2                                                                             H         OCH.sub.3                                        H    N(CH.sub.3).sub.2                                                                             6-Cl      CH.sub.3                                         H    N(CH.sub.3).sub.2                                                                             5-OCH.sub.3                                                                              CH.sub.3                                         H    N(CH.sub.3).sub.2                                                                             5-SCH.sub.3                                                                              CH.sub.3                                         H    N(CH.sub.3).sub.2                                                                             5-N(CH.sub.3).sub.2                                                                      CH.sub.3                                         H    N(CH.sub.3).sub.2                                                                             5-NO.sub.2                                                                               CH.sub.3                                         H    N(CH.sub.3).sub.2                                                                             6-CH.sub.3                                                                               CH.sub.3                                         H    N(CH.sub.3).sub.2                                                                             6-CF.sub.3                                                                               CH.sub.3                                         H    N(CH.sub.3)C.sub.4 H.sub.9                                                                    H         CH.sub.3                                         H    N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                           H         CH.sub.3                                         H    N(OH)CH.sub.3  H         CH.sub.3                                         H    N(CH.sub.3)CH.sub.2 OH                                                                        H         CH.sub.3                                         H    NHCN           H         CH.sub.3                                         H    P(O)(OCH.sub.3).sub.2                                                                         H         CH.sub.3                                         H    P(O)(CH.sub.3)OCH.sub.3                                                                       H         CH.sub.3                                         H    P(S)(CH.sub.3)OCH.sub.3                                                                       H         CH.sub. 3                                        H    P.sup.+ (C.sub.6 H.sub.5).sub.3                                                               H         CH.sub.3                                         H    SCH.sub.3      H         CH.sub.3                                         H    SO.sub.2 CH.sub.3                                                                             H         CH.sub.3                                         H    CH.sub.2 NO.sub.2                                                                             H         CH.sub.3                                         H    CH(CN).sub.2   H         CH.sub.3                                         ______________________________________                                    

                  TABLE XXVI                                                       ______________________________________                                         General Formula XXVI                                                                                                             m.p.                         Q    R     R.sub.2                                                                              R.sub.4                                                                             R.sub.5                                                                             R.sub.6                                                                             R.sub.9                                                                             R.sub.12 R.sub.13                                                                      R.sub.14                                                                            (°C.)                 ______________________________________                                         Q-1  H     H     --   --   --   --   OCH.sub.3 --                                                                           --                                Q-1  H     H     --   --   --   --   CH.sub.3 --                                                                            --                                Q-2  H     H     --   --   --   CH.sub.3                                                                            OCH.sub.3 --                                                                           --                                Q-2  H     H     --   --   --   CH.sub.3                                                                            CH.sub.3 --                                                                            --                                Q-3  H     H     --   --   --   --   OCH.sub.3 --                                                                           --                                Q-3  H     H     --   --   --   --   CH.sub.3 --                                                                            --                                Q-4  H     H     --   --   --   --   OCH.sub.3 --                                                                           --                                Q-4  H     H     --   --   --   --   CH.sub.3 --                                                                            --                                Q-5  H     H     --   --   --   --   ----    --                                Q-6  H     H     --   --   --   --   ----    --                                Q-7  H     H     --   --   --   --   ----    --                                Q-8  H     H     --   --   --   --   --H     H                                 Q-9  H     H     CH.sub.3                                                                            CH.sub.3                                                                            --   --   --H     H                                 Q-10 H     H     --   --   --   --   --H     H                                 Q-11 H     H     CH.sub.3                                                                            CH.sub.3                                                                            --   --   --CH.sub.3                                                                             H                                 Q-12 H     H     --   --   --   --   --CH.sub.3                                                                             H                                 Q-13 H     H     --   --   CH.sub.3                                                                            CH.sub.3                                                                            ----    --                                Q-14 H     H     --   --   CH.sub.3                                                                            CH.sub.3                                                                            ----    --                                ______________________________________                                    

                  TABLE XXVII                                                      ______________________________________                                         General Formula XXVII                                                          R   R.sub.1        R.sub.2      X.sub.1                                                                             m.p. (°C.)                         ______________________________________                                         H   N(CH.sub.3).sub.2                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             NO.sub.2     CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             CF.sub.3     CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             OCH.sub.3    CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             SCH.sub.3    CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                                  CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             SO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             OSO.sub.2 CH.sub.3                                                                          CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             OCH.sub.2 CH═CH.sub.2                                                                   CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             CH.sub.3     CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             Cl           CH.sub.3                                       H   N(CH.sub.3)C.sub.4 H.sub.9                                                                    CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                           CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   N(CH.sub.3)CH.sub.2 OH                                                                        CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   NHCN           CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   P(O)(OCH.sub.3).sub.2                                                                         CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   P(O)(CH.sub.3)OCH.sub.3                                                                       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   P(S)(CH.sub.3)OCH.sub.3                                                                       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                               CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   SO.sub.2 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   CH.sub.2 NO.sub.2                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       ______________________________________                                    

                  TABLE XXVIII                                                     ______________________________________                                         General Formula XXVIII                                                                                                 m.p.                                   Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                              R.sub.14            (°C.)                           ______________________________________                                         Q-1  H     CO.sub.2 CH.sub.3                                                                       --------OCH.sub.3 ----                                     Q-1  H     CO.sub.2 CH.sub.3                                                                       --------CH.sub.3 ----                                      Q-2  H     CO.sub.2 CH.sub.3                                                                       ------CH.sub.3 OCH.sub.3 ----                              Q-2  H     CO.sub.2 CH.sub.3                                                                       ------CH.sub.3 CH.sub.3 ----                               Q-3  H     CO.sub.2 CH.sub.3                                                                       --------OCH.sub.3 ----                                     Q-3  H     CO.sub.2 CH.sub.3                                                                       --------CH.sub.3 ----                                      Q-4  H     CO.sub.2 CH.sub.3                                                                       --------OCH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                       --------CH.sub.3 ----                                      Q-5  H     CO.sub.2 CH.sub.3                                                                       --------------                                             Q-6  H     CO.sub.2 CH.sub.3                                                                       --------------                                             Q-7  H     CO.sub.2 CH.sub.3                                                                       --------------                                             Q-8  H     CO.sub.2 CH.sub.3                                                                       ----------HH                                               Q-9  H     CO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3 ------HH                                 Q-10 H     CO.sub.2 CH.sub.3                                                                       ----------HH                                               Q-11 H     CO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3 ------CH.sub.3 H                         Q-12 H     CO.sub.2 CH.sub.3                                                                       ----------CH.sub.3 H                                       Q-13 H     CO.sub.2 CH.sub.3                                                                       ----CH.sub.3 CH.sub.3 ------                               Q-14 H     CO.sub.2 CH.sub.3                                                                       ----CH.sub.3 CH.sub.3 ------                               ______________________________________                                    

                  TABLE XXIX                                                       ______________________________________                                         General Formula XXIX                                                                                                   m.p.                                   R    R.sub.1         R.sub.2       X.sub.1                                                                             (°C.)                           ______________________________________                                         H    N(CH.sub.3).sub.2                                                                              CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    N(CH.sub.3).sub.2                                                                              NO.sub.2      CH.sub.3                                    H    N(CH.sub.3).sub.2                                                                              CF.sub.3      CH.sub.3                                    H    N(CH.sub.3).sub.2                                                                              OCH.sub.3     CH.sub.3                                    H    N(CH.sub.3).sub.2                                                                              SCH.sub.3     CH.sub.3                                    H    N(CH.sub.3).sub.2                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                                   CH.sub.3                                    H    N(CH.sub.3).sub.2                                                                              SO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    N(CH.sub.3).sub.2                                                                              OSO.sub.2 CH.sub.3                                                                           CH.sub.3                                    H    N(CH.sub.3).sub.2                                                                              CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                    H    N(CH.sub.3).sub.2                                                                              OCH.sub.2 CH═CH.sub.2                                                                    CH.sub.3                                    H    N(CH.sub.3).sub.2                                                                              CH.sub.3      CH.sub.3                                    H    N(CH.sub.3).sub.2                                                                              Cl            CH.sub.3                                    H    N(CH.sub.3)C.sub.4 H.sub.9                                                                     CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                            CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    N(OH)CH.sub.3   CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    N(CH.sub.3)CH.sub.2 OH                                                                         CO.sub.2 CH.sub. 3                                                                           CH.sub.3                                    H    NHCN            CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    P(O)(OCH.sub.3).sub.2                                                                          CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    P(O)(CH.sub.3)OCH.sub.3                                                                        CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    P(S)(CH.sub.3)OCH.sub.3                                                                        CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    P.sup.+ (C.sub.6 H.sub.5).sub.3                                                                CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    SCH.sub.3       CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    SO.sub.2 CH.sub.3                                                                              CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    CH.sub.2 NO.sub.2                                                                              CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    H    CH(CN).sub.2    CO.sub.2 CH.sub.3                                                                            CH.sub.3                                    ______________________________________                                    

                  TABLE XXX                                                        ______________________________________                                         General Formula XXX                                                                                                    m.p.                                   Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                              R.sub.14            (°C.)                           ______________________________________                                         Q-1  H     CO.sub.2 CH.sub.3                                                                       --------OCH.sub.3 ----                                     Q-1  H     CO.sub.2 CH.sub.3                                                                       --------CH.sub.3 ----                                      Q-2  H     CO.sub.2 CH.sub.3                                                                       ------CH.sub.3 OCH.sub.3 ----                              Q-2  H     CO.sub.2 CH.sub.3                                                                       ------CH.sub.3 CH.sub.3 ----                               Q-3  H     CO.sub.2 CH.sub.3                                                                       --------OCH.sub.3 ----                                     Q-3  H     CO.sub.2 CH.sub.3                                                                       --------CH.sub.3 ----                                      Q-4  H     CO.sub.2 CH.sub.3                                                                       --------OCH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                       --------CH.sub.3 ----                                      Q-5  H     CO.sub.2 CH.sub.3                                                                       --------------                                             Q-6  H     CO.sub.2 CH.sub.3                                                                       --------------                                             Q-7  H     CO.sub.2 CH.sub.3                                                                       --------------                                             Q-8  H     CO.sub.2 CH.sub.3                                                                       ----------HH                                               Q-9  H     CO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3 ------HH                                 Q-10 H     CO.sub.2 CH.sub.3                                                                       ----------HH                                               Q-11 H     CO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3 ------CH.sub.3 H                         Q-12 H     CO.sub.2 CH.sub.3                                                                       ----------CH.sub.3 H                                       Q-13 H     CO.sub.2 CH.sub.3                                                                       ----CH.sub.3 CH.sub.3 ------                               Q-14 H     CO.sub.2 CH.sub.3                                                                       ----CH.sub.3 CH.sub.3 ------                               ______________________________________                                    

                  TABLE XXXI                                                       ______________________________________                                         General Formula XXXI                                                           R   R.sub.1        R.sub.2      X.sub.1                                                                             m.p. (°C.)                         ______________________________________                                         H   N(CH.sub.3).sub.2                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             NO.sub.2     CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             CF.sub.3     CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             OCH.sub.3    CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             SCH.sub.3    CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             SO.sub.2 N(CH.sub.3).sub.2                                                                  CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             SO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             OSO.sub.2 CH.sub.3                                                                          CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             OCH.sub.2 CH═CH.sub.2                                                                   CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             CH.sub.3     CH.sub.3                                       H   N(CH.sub.3).sub.2                                                                             Cl           CH.sub.3                                       H   N(CH.sub.3)C.sub.4 H.sub.9                                                                    CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                           CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   N(CH.sub.3)CH.sub.2 OH                                                                        CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   NHCN           CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   P(O)(OCH.sub.3).sub.2                                                                         CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   P(O)(CH.sub.3)OCH.sub.3                                                                       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   P(S)(CH.sub.3)OCH.sub.3                                                                       CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                               CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   SO.sub.2 CH.sub.3                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   CH.sub.2 NO.sub.2                                                                             CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                           CH.sub.3                                       ______________________________________                                    

                  TABLE XXXII                                                      ______________________________________                                         General Formula XXXII                                                                                                    m.p.                                 Q    RR.sub.3  R.sub.4 R.sub.5                                                                         R.sub.6 R.sub.9                                                                       R.sub.12                                                                             R.sub.13                                                                            R.sub.14(°C.)                 ______________________________________                                         Q-1  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-1  HCO.sub.2 CH.sub.3                                                                       ----     ---    CH.sub.3                                                                             --   --                                   Q-2  HCO.sub.2 CH.sub.3                                                                       ----     --CH.sub.3                                                                            OCH.sub.3                                                                            --   --                                   Q-2  HCO.sub.2 CH.sub.3                                                                       ----     --CH.sub.3                                                                            CH.sub.3                                                                             --   --                                   Q-3  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-3  HCO.sub.2 CH.sub.3                                                                       ----     ----   CH.sub.3                                                                             --   --                                   Q-4  HCO.sub.2 CH.sub.3                                                                       ----     ----   OCH.sub.3                                                                            --   --                                   Q-4  HCO.sub.2 CH.sub. 3                                                                      ----     ----   CH.sub.3                                                                             --   --                                   Q-5  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-6  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-7  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    --   --                                   Q-8  HCO.sub.2 CH.sub.3                                                                       ----     ----   --    H    H                                    Q-9  HCO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3                                                                       ----   --    H    H                                    Q-10 HCO.sub.2 CH.sub.3                                                                       ----     ----   --    H    H                                    Q-11 HCO.sub.2 CH.sub.3                                                                       CH.sub.3 CH.sub.3                                                                       ----   --    CH.sub.3                                                                            H                                    Q-12 HCO.sub.2 CH.sub.3                                                                       ----     ----   --    CH.sub.3                                                                            H                                    Q-13 HCO.sub.2 CH.sub.3                                                                       ----     CH.sub.3 CH.sub.3                                                                     --    --   --                                   Q-14 HCO.sub.2 CH.sub.3                                                                       ----     CH.sub.3 CH.sub.3                                                                     --    --   --                                   ______________________________________                                    

Formulations

Useful formulations of the compounds of Formula I and II can be prepared in conventional ways. They include dusts, granules, pellets, solutions, suspensions, emulsions, wettable powders, emulsifiable concentrates and the like. Many of these may be applied directly. Sprayable formulations can be extended in suitable media and used at spray volumes of from a few liters to several hundred liters per hectare. High strength compositions are primarily used as intermediates for further formulation. The formulations, broadly, contain about 0.1% to 99% by weight of active ingredient(s) and at least one of (a) about 0.1% to 20% surfactant(s) and (b) about 1% to 99.9% solid or liquid inert diluent(s). More specifically, they will contain these ingredients in the following approximate proportions:

                  TABLE XXXIII                                                     ______________________________________                                                     Weight Percent*                                                                Active                                                                         Ingredient                                                                             Diluent(s)                                                                               Surfactant(s)                                    ______________________________________                                         Wettable Powders                                                                             20-90      0-74     1-10                                         Oil Suspensions,                                                                              3-50     40-95     0-15                                         Emulsions, Solutions,                                                          (including Emulsifiable                                                        Concentrates)                                                                  Aqueous Suspension                                                                           10-50     40-84     1-20                                         Dusts          1-25     70-99     0-5                                          Granules and Pellets                                                                         0.1-95      5-99.9  0-15                                         High Strength 90-99      0-10     0-2                                          Compositions                                                                   ______________________________________                                          *Active ingredient plus at least one of a Surfactant or a Diluent equals       100 weight percent.                                                      

Lower or higher levels of active ingredient can, of course, be present depending on the intended use and the physical properties of the compound. Higher ratios of surfactant to active ingredient are sometimes desirable, and are achieved by incorporation into the formulation or by tank mixing.

Typical solid diluents are described in Watkins, et al., "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Dorland Books, Caldwell, N.J., but other solids, either mined or manufactured, may be used. The more absorptive diluents are preferred for wettable powders and the denser ones for dusts. Typical liquid diluents and solvents are described in Marsden, "Solvents Guide," 2nd Ed., Interscience, New York, 1950. Solubility under 0.1% is preferred for suspension concentrates; solution concentrates are preferably stable against phase separation at 0° C. "McCutcheon's Detergents and Emulsifiers Annual", MC Publishing Corp., Ridgewood, N.J., as well as Sisely and Wood, "Encyclopedia of Surface Active Agents", Chemical Publishing Co., Inc., New York, 1964, list surfactants and recommended uses. All formulations can contain minor amounts of additives to reduce foaming, caking, corrosion, microbiological growth, etc.

The methods of making such compositions are well known. Solutions are prepared by simply mixing the ingredients. Fine solid compositions are made by blending and, usually, grinding as in a hammer or fluid energy mill. Suspensions are prepared by wet milling (see, for example, Littler, U.S. Pat. No. 3,060,084). Granules and pellets may be made by spraying the active material upon preformed granular carriers or by agglomeration techniques. See J. E. Browning, "Agglomeration", Chemical Engineering, Dec. 4, 1967, pp. 147ff, and "Perry's Chemical Engineer's Handbook", 5th Ed., McGraw-Hill, New York, 1973, pp. 8-57ff.

For further information regarding the art of formulation, see for example:

H. M. Loux, U.S. Pat. No. 3,235,361, Feb. 15, 1966, Col. 6, line 16 through Col. 7, line 19 and Examples 10 through 41;

R. W. Luckenbaugh, U.S. Pat. No. 3,309,192, Mar. 14, 1967, Col. 5, line 43 through Col. 7, line 62 and Examples 8, 12, 15, 39, 41, 52, 53, 58, 132, 138-140, 162-164, 166, 167 and 169-182;

H. Gysin and E. Knusli, U.S. Pat. No. 2,891,855, June 23, 1959, Col. 3, line 66 through Col. 5, line 17 and Examples 1-4;

G. C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York, 1961, pp. 81-96; and

J. D. Fryer and S. A. Evans, "Weed Control Handbook", 5th Ed., Blackwell Scientific Publications, Oxford, 1968, pp. 101-103.

In the following examples, all parts are by weight unless otherwise indicated.

EXAMPLE 4 Wettable Powder

    ______________________________________                                         2-[4-(dimethylamino)phenylazo]-N--[(4-methoxy-6-                                                           80%                                                methylpyrimidin-2-yl)aminocarbonyl]benzene-                                    sulfonamide                                                                    sodium alkylnaphthalenesulfonate                                                                            2%                                                sodium ligninsulfonate       2%                                                synthetic amorphous silica   3%                                                kaolinite                   13%                                                ______________________________________                                    

The ingredients are blended, hammer-milled until all the solids are essentially under 50 microns, reblended, and packaged.

EXAMPLE 5 Wettable Powder

    ______________________________________                                         [[2-[[(4-methoxy-6-methylpyrimidin-2-yl)amino-                                                           50%                                                  carbonyl]aminosulfonyl]phenyl]azo]phosphonic                                   acid, dimethylester                                                            sodium alkylnaphthalenesulfonate                                                                          2%                                                  low viscosity methyl cellulose                                                                            2%                                                  diatomaceous earth        46%                                                  ______________________________________                                    

The ingredients are blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in diameter. The product is reblended before packaging.

EXAMPLE 6 Granule

    ______________________________________                                         Wettable Powder of Example 5                                                                           5%                                                     attapulgite granules   95%                                                     (U.S.S. 20-40 mesh: 0.84-0.42 mm)                                              ______________________________________                                    

A slurry of wettable powder containing 25% solids is sprayed on the surface of attapulgite granules in a double-cone blender. The granules are dried and packaged.

EXAMPLE 7 Extruded Pellet

    ______________________________________                                         2-(dimethyl-1-triazeno)-N--[(4-methoxy-6-methyl-                                                           25%                                                pyrimidin-2-yl)aminocarbonyl]benzenesulfon-                                    amide                                                                          anhydrous sodium sulfate    10%                                                crude calcium ligninsulfonate                                                                               5%                                                sodium alkylnaphthalenesulfonate                                                                            1%                                                calcium/magnesium bentonite 59%                                                ______________________________________                                    

The ingredients are blended, hammer-milled and then moistened with about 12% water. The mixture is extruded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets may be crushed to pass a U.S.S. No. 20 sieve (0.84 mm openings). The granules held on a U.S.S. No. 40 sieve (0.42 mm openings) may be packaged for use and the fines recycled.

EXAMPLE 8 Oil Suspension

    ______________________________________                                         [[2-[[(4-methoxy-6-methylpyrimidin-2-yl)amino-                                                           25%                                                  carbonyl]aminosulfonyl]phenyl]azo]phosphonic                                   acid, dimethylester                                                            polyoxyethylene sorbitol hexaoleate                                                                       5%                                                  highly aliphatic hydrocarbon oil                                                                         70%                                                  ______________________________________                                    

The ingredients are ground together in a sand mill until the solid particles have been reduced to under about 5 microns. The resulting thick suspension may be applied directly, but preferably after being extended with oils or emulsified in water.

EXAMPLE 9 Wettable Powder

    ______________________________________                                         2-(dimethyl-1-triazeno)-N--[(4-methoxy-6-methyl-                                                           20%                                                pyrimidin-2-yl)aminocarbonyl]benzenesulfon-                                    amide                                                                          sodium alkylnaphthalenesulfonate                                                                            4%                                                sodium ligninsulfonate       4%                                                low viscosity methyl cellulose                                                                              3%                                                attapulgite                 69%                                                ______________________________________                                    

The ingredients are thoroughly blended. After grinding in a hammer-mill to produce particles essentially all below 100 microns, the material is reblended and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) and packaged.

EXAMPLE 10 Low Strength Granule

    ______________________________________                                         2-(dimethyl-1-triazeno)-N--[(4-methoxy-6-methyl-                                                            1%                                                pyrimidin-2-yl)aminocarbonyl]benzenesulfon-                                    amide                                                                          N,N--dimethylformamide       9%                                                attapulgite granules        90%                                                (U.S.S. 20-40 sieve)                                                           ______________________________________                                    

The active ingredient is dissolved in the solvent and the solution is sprayed upon dedusted granules in a double cone blender. After spraying of the solution has been completed, the blender is allowed to run for a short period and then the granules are packaged.

EXAMPLE 11 Aqueous Suspension

    ______________________________________                                         2-[4-(dimethylamino)phenylazo]-N--[(4-methoxy-6-                                                           40%                                                methylpyrimidin-2-yl)aminocarbonyl]benzene-                                    sulfonamide                                                                    polyacrylic acid thickener   0.3%                                              dodecylphenol polyethylene glycol ether                                                                     0.5%                                              disodium phosphate           1%                                                monosodium phosphate         0.5%                                              polyvinyl alcohol            1.0%                                              water                       56.7%                                              ______________________________________                                    

The ingredients are blended and ground together in a sand mill to produce particles essentially all under 5 microns in size.

EXAMPLE 12 Solution

    ______________________________________                                         [[2-[[(4-methoxy-6-methylpyrimidin-2-yl)amino-                                                            5%                                                  carbonyl]aminosulfonyl]phenyl]azo]phosphonic                                   acid, dimethylester, sodium salt                                               water                     95%                                                  ______________________________________                                    

The salt is added directly to the water with stirring to produce the solution, which may then be packaged for use.

EXAMPLE 13 Low Strength Granule

    ______________________________________                                         2-[4-(dimethylamino)phenylazo]-N--[(4-methoxy-6-                                                          0.1%                                                methylpyrimidin-2-yl)aminocarbonyl]benzene-                                    sulfonamide                                                                    attapulgite granules      99.9%                                                (U.S.S. 20-40 mesh)                                                            ______________________________________                                    

The active ingredient is dissolved in a solvent and the solution is sprayed upon dedusted granules in a double-cone blender. After spraying of the solution has been completed, the material is warmed to evaporate the solvent. The material is allowed to cool and then packaged.

EXAMPLE 14 Granule

    ______________________________________                                         [[2-[[(4-methoxy-6-methylpyrimidin-2-yl)amino-                                                           80%                                                  carbonyl]aminosulfonyl]phenyl]azo]phosphonic                                   acid, dimethylester                                                            wetting agent              1%                                                  crude ligninsulfonate salt (containing                                                                   10%                                                  5-20% of the natural sugars)                                                   attapulgite clay           9%                                                  ______________________________________                                    

The ingredients are blended and milled to pass through a 100 mesh screen. This material is then added to a fluid bed granulator, the air flow is adjusted to gently fluidize the material, and a fine spray of water is sprayed onto the fluidized material. The fluidization and spraying are continued until granules of the desired size range are made. The spraying is stopped, but fluidization is continued, optionally with heat, until the water content is reduced to the desired level, generally less than 1%. The material is then discharged, screened to the desired size range, generally 14-100 mesh (1410-149 microns), and packaged for use.

EXAMPLE 15 High Strength Concentrate

    ______________________________________                                         2-(dimethyl-1-triazeno)-N--[(4-methoxy-6-methyl-                                                           99%                                                pyrimidin-2-yl)aminocarbonyl]benzenesulfonamide                                silica aerogel             0.5%                                                synthetic amorphous silica 0.5%                                                ______________________________________                                    

The ingredients are blended and ground in a hammer-mill to produce a material essentially all passing a U.S.S. No. 50 screen (0.3 mm opening). The concentrate may be formulated further if necessary.

EXAMPLE 16 Wettable Powder

    ______________________________________                                         2-[4-(dimethylamino)phenylazo]-N--[(4-methoxy-6-                                                           90%                                                methylpyrimidin-2-yl)aminocarbonyl]benzene-                                    sulfonamide                                                                    dioctyl sodium sulfosuccinate                                                                             0.1%                                                synthetic fine silica      9.9%                                                ______________________________________                                    

The ingredients are blended and ground in a hammer-mill to produce particles essentially all below 100 microns. The material is sifted through a U.S.S. No. 50 screen and then packaged.

EXAMPLE 17 Wettable Powder

    ______________________________________                                         [[2-[[(4-methoxy-6-methylpyrimidin-2-yl)amino-                                                           40%                                                  carbonyl]aminosulfonyl]phenyl]azo]phosphonic                                   acid, dimethylester                                                            sodium ligninsulfonate    20%                                                  montmorillonite clay      40%                                                  ______________________________________                                    

The ingredients are thoroughly blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in size. The material is reblended and then packaged.

EXAMPLE 18 Oil Suspension

    ______________________________________                                         2-(dimethyl-1-triazeno)-N--[(4-methoxy-6-methyl-                                                           35%                                                pyrimidin-2-yl)aminocarbonyl]benzenesulfon-                                    amide                                                                          blend of polyalcohol carboxylic                                                                             6%                                                esters and oil soluble petroleum                                               sulfonates                                                                     xylene                      59%                                                ______________________________________                                    

The ingredients are combined and ground together in a sand mill to produce particles essentially all below 5 microns. The product can be used directly, extended with oils, or emulsified in water.

EXAMPLE 19 Dust

    ______________________________________                                         2-[4-(dimethylamino)phenylazo]-N--[(4-methoxy-6-                                                           10%                                                methylpyrimidin-2-yl)aminocarbonyl]benzene-                                    sulfonamide                                                                    attapulgite                 10%                                                Pyrophyllite                80%                                                ______________________________________                                    

The active ingredient is blended with attapulgite and then passed through a hammer-mill to produce particles substantially all below 200 microns. The ground concentrate is then blended with powdered pyrophyllite until homogeneous.

Utility

Test results indicate that the compounds of the present invention are highly active preemergent or postemergent herbicides or plant growth regulants. Many of them have utility for broad-spectrum pre- and or post-emergence weed control in areas where complete control of all vegetation is desired, such as around fuel storage tanks, ammunition depots, industrial storage areas, parking lots, drive-in theaters, around billboards, highway and railroad structures. Some of the compounds have utility for selective weed control in crops such as wheat and cotton. Alternatively, the subject compounds are useful to modify plant growth.

The rates of application for the compounds of the invention are determined by a number of factors, including their use as plant growth modifiers or as herbicides, the crop species involved, the types of weeds to be controlled, weather and climate, formulations selected, mode of application, amount of foliage present, etc. In general terms, the subject compounds should be applied at levels of around 0.01 to 10 kg of active ingredient per hectare, the lower rates being suggested for use on lighter soils and/or those having a low organic matter content, for selective weed control or for situations where only short-term persistence is required.

The compounds of the invention may be used in combination with any other commercial herbicide; examples of which are those of the triazine, triazole, uracil, urea, amide, diphenylether, carbamate and bipyridylium types.

The herbicidal properties of the subject compounds were discovered in a number of greenhouse tests. The test procedures and results follow. ##STR40##

Test A

Seeds of crabgrass (Digitaria sp.), barnyardgrass (Echinochloa crusgalli), wild oats (Avena fatua), velvetleaf (Abutilon theophrasti), morningglory (Ipomoea spp.), cocklebur (Xanthium pensylvanicum), sicklepod (Cassia obtusifolia), cheatgrass (Bromus secalinus), bushbean, sorghum, corn, soybean, sugarbeet, cotton, rice, wheat and purple nutsedge (Cyperus rotundus) tubers were planted and treated preemergence with the test chemicals dissolved in a non-phytotoxic solvent. At the same time, these crop and weed species were treated with a soil/foliage application. At the time of treatment, the plants ranged in height from 2 to 18 cm. Treated plants and controls were maintained in a greenhouse for sixteen days, after which all species were compared to controls and visually rated for response to treatment. The ratings, summarized in Table A, are based on a numerical scale extending from 0=no injury, to 10=complete kill. The accompanying descriptive symbols have the following meanings:

C=chlorosis/necrosis;

B=burn;

D=defoliation;

E=emergence inhibition;

G=growth retardation;

H=formative effect;

U=unusual pigmentation;

X=axillary stimulation;

S=albinism; and

6Y=abscised buds or flowers.

                                      TABLE A                                      __________________________________________________________________________     Compound 1                                                                                                                BARN-                               TYPE                                                                               RATE                                                                               BUSH-                                                                              COT-                                                                               SOR-     SOY-     WILD-    YARD-                               TEST                                                                               G/HA                                                                               BEAN                                                                               TON GHUM CORN                                                                               BEAN                                                                               WHEAT                                                                               OATS RICE                                                                               GRASS                               __________________________________________________________________________     Post                                                                               100 9C  8C  5U   5U  4C  7G   3C   4C  5C                                              9G  9G   9G  9G       5G   9G  9H                                  Pre 100 --  --  1C   1C  5H  1C   1C   10E 1C                                                  9G   6G      5G   5G       9H                                  __________________________________________________________________________                  MORN-                                                                               COCK-                                                                               SICK-                                                   TYPE                                                                               RATE                                                                               CRAB-                                                                               ING- LE-  LE- NUT- SUGAR-                                                                              VELVET-                                                                              CHEAT-                              TEST                                                                               G/HA                                                                               GRASS                                                                               GLORY                                                                               BUR  POD SEDGE                                                                               BEETS                                                                               LEAF  GRASS                               __________________________________________________________________________     Post                                                                               100 2C   10C  9C   6C  1C   --   --    --                                          6G             9G  8G                                                  Pre 100 3C   8G   9H   9G  10E  --   --    --                                          8G                                                                     __________________________________________________________________________     Compound 2                                                                                                                 BARN-                              TYPE                                                                               RATE                                                                               BUSH-                                                                              COT-                                                                               SOR-     SOY-     WILD-    YARD-                               TEST                                                                               G/HA                                                                               BEAN                                                                               TON GHUM CORN                                                                               BEAN                                                                               WHEAT                                                                               OATS RICE                                                                               GRASS                               __________________________________________________________________________     Post                                                                               400 6C  3C  3C   5C  6C  0    0    --  2C                                          9G  3H  9G   9H  9G                9H                                          6Y  8G                                                                 Pre 400 --  -1C 1C   5H  5H  1C   1C   10E 2C                                              9G  9H           6G   5G       8H                                  __________________________________________________________________________                  MORN-                                                                               COCK-                                                                               SICK-                                                   TYPE                                                                               RATE                                                                               CRAB-                                                                               ING- LE-  LE- NUT- SUGAR-                                                                              VELVET-                                                                              CHEAT-                              TEST                                                                               G/HA                                                                               GRASS                                                                               GLORY                                                                               BUR  POD SEDGE                                                                               BEETS                                                                               LEAF  GRASS                               __________________________________________________________________________     Post                                                                               400 2C   8C   2C   2C  2C   --   --    --                                                    7G   6G  8G                                                  Pre 400 2C   9G   9H   9G  10E  --   --    --                                          8G                                                                     __________________________________________________________________________     Compound 3                                                                                                                BARN-                               TYPE                                                                               RATE                                                                               BUSH-                                                                              COT-                                                                               SOR-     SOY-     WILD-    YARD-                               TEST                                                                               G/HA                                                                               BEAN                                                                               TON GHUM CORN                                                                               BEAN                                                                               WHEAT                                                                               OATS RICE                                                                               GRASS                               __________________________________________________________________________     Post                                                                               400 --  4C  3C   3C  3C  5C   3C   5C  3C                                              9G  9G   9H  9G  9G   9G   9G  9H                                  Post                                                                                50 --  2C  3C   3C  4C  0    0    5C  3C                                              9G  9H   9G  9G            9G  9H                                  Pre 400 --  9G  3C   3C  8G  2C   2C   10E 2C                                                  9H   9G      9G   9G       9H                                  Pre  50 --  2C  3C   2C  3C  8G   2C   3C  2C                                              8G  8H   9G  7G       8G   8G  7G                                  __________________________________________________________________________                  MORN-                                                                               COCK-                                                                               SICK-                                                   TYPE                                                                               RATE                                                                               CRAB-                                                                               ING- LE-  LE- NUT- SUGAR-                                                                              VELVET-                                                                              CHEAT-                              TEST                                                                               G/HA                                                                               GRASS                                                                               GLORY                                                                               BUR  POD SEDGE                                                                               BEETS                                                                               LEAF  GRASS                               __________________________________________________________________________     Post                                                                               400 4G   3C   3C   5C  2C   4C   --    --                                               9G   9G   9G  9G   9G                                             Post                                                                                50 2G   0    1C   3C  2C   5C   --    --                                                    2G   8G  8G   9G                                             Pre 400 5G   9G   9H   9G  9G   5C   --    --                                                                  9G                                             Pre  50 0    8G   9H   8G  7G   4C   --    --                                                                  9G                                             __________________________________________________________________________     Compound 4                                                                                                                BARN-                               TYPE                                                                               RATE                                                                               BUSH-                                                                              COT-                                                                               SOR-     SOY-     WILD-    YARD-                               TEST                                                                               G/HA                                                                               BEAN                                                                               TON GHUM CORN                                                                               BEAN                                                                               WHEAT                                                                               OATS RICE                                                                               GRASS                               __________________________________________________________________________     Post                                                                                50 --  10C 3C   3C  5C  3C   3C   6C  9H                                                  9H   9H  9H  6G   7G   9G                                      Pre  50 --  9G  5C   3C  3C  8G   3C   4C  3C                                                  9H   9H  8H       8G   8G  9H                                  __________________________________________________________________________                  MORN-                                                                               COCK-                                                                               SICK-                                                   TYPE                                                                               RATE                                                                               CRAB-                                                                               ING- LE-  LE- NUT- SUGAR-                                                                              VELVET-                                                                              CHEAT-                              TEST                                                                               G/HA                                                                               GRASS                                                                               GLORY                                                                               BUR  POD SEDGE                                                                               BEETS                                                                               LEAF  GRASS                               __________________________________________________________________________     Post                                                                                50 6G   3C   4C   --  6G   0C   9C    3C                                               7G   8H                       7G                                  Pre  50 4G   7G   8H   --  3C   10C  10C   9H                                                             5G                                                  __________________________________________________________________________

Test B

Two 25 cm diameter plastic containers were lined with plastic bags and filled with Woodstown sandy loam. A 25 cm diameter Lucite® planting template was used to slightly compress the soil within each container and to provide indentations for the planting of nine crop or weed species. Seeds of the following species were placed in one container: mustard (Brassica nigra), cocklebur (Xantium pensylvanicum), velvetleaf (Abutilon theophrasti), sugar beets (Beta vulgaris), sicklepod (Cassia obtusifolia), morningglory (Ipomoea spp.), purle nutsedge (Cyperus rotundus), pigweed (Amaranthus retroflexus), teaweed (Sida spinosa), cotton (Gossypium hirsutum), jimsonweed (Datura stramonium) and soybean (Glycine max.). The second pot was planted with seeds of the following species: sorghum, (Sorghum bicolor), rice (Oryza sativa), giant foxtail (Setaria faberii), Dallisgrass (Paspalum diltatum), crabgrass (Digitaria sanguinalis), bluegrass (Poa pratensis), johnsongrass (Sorghum halepense), wild oats (Avena fatua), wheat (Triticum aestivum), cheatgrass (Bromus secalinus), barnyardgrass (Echinochloa crusgalli), and corn (Zea mays). Both containers were then topped with an approximately 1 cm layer of soil to cover the seeds. These two containers were then sprayed preemergence with the test compounds indicated in Table B. Following treatment, the plants were placed under an automatic overhead water device, where they received approximately 1 cm of simulated rainfall in a period of 150 minutes.

Approximately twenty-eight days after treatment, the plants were visually rated for response to the chemical treatments utilizing the rating system as described for Test A. The resuls are presented in Table B.

                                      TABLE B                                      __________________________________________________________________________     Compound 1                                                                             BARN-                    JOHN-                                                                               DAL- GIANT-                              RATE    YARD      WILD-                                                                               CRAB-                                                                               SOR- SON- LIS- FOX- BLUE-                                                                               CHEAT-                    G/HA                                                                               RICE                                                                               GRASS                                                                               WHEAT                                                                               OATS GRASS                                                                               GHUM GRASS                                                                               GRASS                                                                               TAIL GRASS                                                                               GRASS                                                                               CORN                 __________________________________________________________________________     120 8E  7G   0    7G   0    8G   3H   7G   6G   7G   7G   2C                       9G  4C        3C        5H   6G        3C   5C   3C                        31.2                                                                               7G  4G   0    6G   0    5G   0    5G   0    7G   5G   0                                                3H                  3C                             __________________________________________________________________________             COCK-               MORN-           VEL-                                                                               JIM-                           RATE                                                                               MUS-                                                                               LE-  PIG- NUT- COT- ING- SICKLE-                                                                              TEA- VET-                                                                               SON- SOY-                                                                               SUGAR-                G/HA                                                                               TARD                                                                               BUR  WEED SEDGE                                                                               TON  GLORY                                                                               POD   WEED LEAF                                                                               WEED BEAN                                                                               BEETS                 __________________________________________________________________________     120 9G  5G   8G   6G   3H   7G   8G    5G   8G  5G   6G  8G                        9C       9C   3C   7G        9C         7C  3H   3H  8C                    31.2                                                                               8G  6G   8G   3G   2G   0    5G    0    6G  0    0   4G                        3C       8C                             5H                                 __________________________________________________________________________     Compound 2                                                                             BARN-                    JOHN-                                                                               DAL- GIANT-                              RATE    YARD      WILD-                                                                               CRAB-                                                                               SOR- SON- LIS- FOX- BLUE-                                                                               CHEAT-                    G/HA                                                                               RICE                                                                               GRASS                                                                               WHEAT                                                                               OATS GRASS                                                                               GHUM GRASS                                                                               GRASS                                                                               TAIL GRASS                                                                               GRASS                                                                               CORN                 __________________________________________________________________________     250 8G  4G   3G   5G   0    7G   4G   0    0    3G   5G   2G                       3H                      5H                            2H                   62.5                                                                               --  0    --   0    0    0    3G   0    0    0    0    0                    __________________________________________________________________________             COCK-               MORN-           VEL-                                                                               JIM-                           RATE                                                                               MUS-                                                                               LE-  PIG- NUT- COT- ING- SICKLE-                                                                              TEA- VET-                                                                               SON- SOY-                                                                               SUGAR-                G/HA                                                                               TARD                                                                               BUR  WEED SEDGE                                                                               TON  GLORY                                                                               POD   WEED LEAF                                                                               WEED BEAN                                                                               BEETS                 __________________________________________________________________________     250 8G  0    8G   0    0    3G   7G    5G   5G  0    3G  6G                        5C       9C                             5H           4C                    62.5                                                                               8G  0    7G   0    0    3G   0     0    3G  0    4G  4G                    __________________________________________________________________________

Test C

In Test C, plastic pots filled with Fallsington sandy loam were planted to soybeans, cotton, corn, rice, wheat, sorghum, velvetleaf (Abutilon theophrasti), sesbania (Sesbania exaltata), Sicklepod (Cassia obtusifolia), morningglory (Ipomoea hederacea), jimsonweed (Datura stramonium), cocklebur (Xanthium pensylvanicum), crabgrass (Digitaria sp.), nutsedge (Cyperus rotundus), barnyardgrass (Echinochloa crusgalli), giant foxtail (Setaria faberii) and wild oats (Avena fatua). Eighteen days after planting, the young plants and the soil around them were sprayed overall with the test chemicals dissolved in a non-phytotoxic solvent. Fourteen days after treatment, all species were compared to untreated controls and visually rated for response to treatment utilizing the rating system previously described for Test A. The ratings for the compound tested by this procedure are presented in Table C.

                                      TABLE C                                      __________________________________________________________________________     Compound 2                                                                     __________________________________________________________________________                                VEL-      SICK-                                                                              MORN-                                 RATE                                                                               SOY-     COT-         VET-       LE- ING-                                  G/HA                                                                               BEAN                                                                               CORN TON RICE                                                                               WHEAT                                                                               LEAF                                                                               SESBANIA                                                                              POD GLORY                                 __________________________________________________________________________     62  7G  3G   7G  0   0    7G  7G     8G  9G                                        3C  4H   3C           4C  3C     3C  4C                                    250 10G 6G   8G  4G  0    10G 10G    10G 9G                                        4C  3H   5C  3C       8C  5C     6C  4C                                    __________________________________________________________________________         JIM-            BARN-                                                                               GIANT-                                                RATE                                                                               SON- COCKLE-                                                                              CRAB-                                                                               YARD-                                                                               FOX- WILD-                                                                               SOR- NUT-                                   G/HA                                                                               WEED BUR   GRASS                                                                               GRASS                                                                               TAIL OATS GHUM SEDGE                                  __________________________________________________________________________     62  6G   2C    2G   3G   3G   2G   4G   1G                                         3C                                                                         250 6G   6G    5G   7G   5G   6G   7G   1G                                              3C                                                                    __________________________________________________________________________

Test D

Postemergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled with Sassafras sandy loam soil. One pan was planted with blackgrass (Alopecurus myosuroides), sugarbeets, nutsedge (Cyperus rotundus) tubers, crabgrass (Digitaria sanguinalis), sicklepod (Cassia obtusifolia), teaweed (Sida spinosa), jimsonweed (Datura stramonium), velvetleaf (Abutilon theophrasti), and giant foxtail (Setaria faberii). The other pan was planted with wheat, cotton, rice, corn, sugarbeet, soybean, wild oats (Avena fatua), cocklebur (Xanthium pensylvanicum), morningglory (Ipomoea hederacea), johnsongrass (Sorghum halepense) and barnyardgrass (Echinochloa crusgalli). The plants were grown for approximately fourteen days, then sprayed postemergence with the chemicals dissolved in a non-phytoxic solvent.

Preemergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled with Sassafras sandy loam soil. One pan was planted with blackgrass, sugarbeets, nutsedge, crabgrass, sicklepod, teaweed, jimsonweed, velvetleaf, and giant foxtail. The other pan was planted with wheat, cotton, rice, corn, sugarbeet, soybean, wild oats, cocklebur, morningglory, johnsongrass and barnyardgrass. The two pans were sprayed pre-emergence with the chemicals dissolved in a non-phytoxic solvent.

Treated plants and controls were maintained in the greenhouse for 28 days, then all treated plants were compared to controls and visually rated for plant response utilizing the rating system previously described for Test A.

                                      TABLE D                                      __________________________________________________________________________     Compound 2                                                                     __________________________________________________________________________                                              JOHN-     BARN-                       TYPE                                                                               RATE             SOY-      SUGAR-                                                                              CRAB-                                                                               SON- BLACK-                                                                              YARD-                       TEST                                                                               G/HA                                                                               CORN                                                                               WHEAT                                                                               RICE                                                                               BEAN                                                                               COTTON                                                                               BEET GRASS                                                                               GRASS                                                                               GRASS                                                                               GRASS                       __________________________________________________________________________     POST                                                                               250 10G 0    10G 10G 10G   10C  3G   4G   8G   9G                               62 10G 0    10G 9G  9G    10C  0    0    5G   7G                               16 6G  0    6G  8G  4G    7G   0    0    0    3G                               4  2G  0    0   4G  0     3G   0    0    0    0                           PRE 250 9G  0    10E 8G  8G    10G  4G   6G   6G   9G                               62 9G  0    9G  6G  6G    7G   3G   0    3G   4G                               16 3G  0    8G  3G  3G    4G   0    0    0    2G                               4  0   0    3G  0   0     0    0    0    0    0                           __________________________________________________________________________                  GIANT-          MORN-           JIM-                              TYPE                                                                               RATE                                                                               NUT- FOX- WILD-                                                                               COCKLE-                                                                              ING- TEA- SICKLE-                                                                              SON- VELVET-                      TEST                                                                               G/HA                                                                               SEDGE                                                                               TAIL OATS BUR   GLORY                                                                               WEED POD   WEED LEAF                         __________________________________________________________________________     POST                                                                               250 10C  5G   3G   10G   7G   8G   10G   8G   10C                               62 4G   3G   0    5G    5G   5G   3G    5G   10G                               16 0    0    0    0     0    3G   0     0    7G                                4  0    0    0    0     0    0    0     0    2G                           PRE 250 0    3G   3G   9G    0    8G   10E   9G   10G                               62 0    0    0    9G    0    4G   10E   4G   6G                                16 0    0    0    3G    0    2G   4G    2G   4G                                4  0    0    0    0     0    0    0     0    3G                           __________________________________________________________________________ 

What is claimed is:
 1. A compound of Formulae I or II ##STR41## or an agriculturally suitable salt thereof, wherein: R is H or CH₃ ;R₁ is NR₄ R₅, N(CH₃)OR₆, NHCN, NRA, P(W)R₄ (W₁ R₅), P(W)(W₁ R₄)(W₂ R₅), P⁺ (C₆ H₅)₃, P⁺ R₆ R₇ R₈, SR₉, SO₂ R₉, C(R₁₀)(R₁₁)NO₂, CH(CN)₂ or Q; Q is ##STR42## R₂ is H, F, Cl, Br, OCH₃, OC₂ H₅, OCF₂ H, SCH₃ N(CH₃)₂, NO₂, CH₃ or CF₃ ; R₃ is H, F, Cl, Br, C₁ -C₄ alkyl, CO₂ R₁₅, NO₂, CF₃, C₁ -C₄ alkoxy, C₁ -C₄ alkylthio, SO₂ NR₁₆ R₁₇, C₁ -C₄ alkylsulfonyl, C₁ -C₄ haloalkoxy, C₁ -C₄ alkylsulfonyloxy, C₂ -C₅ alkoxyalkyl or C₃ -C₄ alkenyloxy; R₄ and R₅ are independently C₁ -C₄ alkyl, C₂ -C₄ alkyl substituted by 1 atom of Br or 1-3 atoms of F or Cl, C₃ -C₅ alkenyl, C₃ -C₅ cycloalkyl, OH, OCH₃, CH₂ OH, CH₂ OR₆, or CH₂ CH₂ OR₆ ; or R₄ and R₅ when taken together are --(CH₂)₄ --, --(CH₂)₅ -- or --(CH₂)₂ O(CH₂)₂ --; R₆ is C₁ -C₄ alkyl; R₇ and R₈ are independently C₁ -C₄ alkyl; R₉ is C₁ -C₄ alkyl, phenyl or phenyl substituted with 1-3 atoms of F, Cl or 1 Br; R₁₀ and R₁₁ are independently H, C₁ -C₄ alkyl, phenyl or phenyl substituted with 1 atom of Br or 1-3 atoms of F or Cl; R₁₂ is C₁ -C₄ alkyl, C₁ -C₄ alkoxy or NHR₉ ; R₁₃ and R₁₄ are independently H, C₁ -C₃ alkyl, OR₆, SR₆, NHC(O)R₆, F, Cl, Br or CO₂ R₆ ; R₁₅ is C₁ -C₄ alkyl, C₃ -C₄ alkenyl, CH₂ CH₂ Cl or CH₂ CH₂ OCH₃ ; R₁₆ and R₁₇ are independently C₁ -C₂ alkyl; W is O or S; W₁ and W₂ are independently O, S or NH; A is ##STR43## X is CH₃, OCH₃, OCH₂ CH₃, CH₂ F, OCH₂ CH₂ F, OCH₂ CHF₂, OCH₂ CF₃ or CF₃ ; Y is H, C₁ -C₃ alkyl, OCH₃, OC₂ H₅, CH₂ OCH₃, NHCH₃, N(OCH₃)CH₃, N(CH₃)₂, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, CH₂ OCH₂ CH₃, OCH₂ CH₂ OCH₃, CH₂ SCH₃, ##STR44## SCF₂ H or cyclopropyl; m is 2 or 3; L₁ and L₂ are independently O or S; R₁₈ is H or CH₃ ;provided that when Q is Q-11 or Q-12, then R₁₃ is other than H.
 2. A compound of claim 1 wherein R is H.
 3. A compound of claim 2 wherein X is CH₃ or OCH₃ and Y is CH₃, OCH₃, OC₂ H₅, or CH₂ OCH₃.
 4. A compound of claim 3 wherein R₂ is H, Cl, CH₃ or OCH₃ and R₃ is Cl, C₁ -C₃ alkyl, C₁ -C₃ alkoxy, NO₂, CO₂ (C₁ -C₃ alkyl), SO₂ N(CH₃)₂, OSO₂ CH₃, OSO₂ C₂ H₅, SO₂ CH₃, SO₂ C₂ H₅ or allyloxy.
 5. A composition for the control of undesirable vegetation consisting essentially of a compound of claim 1 and at least one of (a) a surface active agent, and (b) a solid or liquid diluent.
 6. A composition for the control of undesirable vegetation consisting essentially of a compound of claim 1 and at least one of (a) a surface active agent, and (b) a solid or liquid diluent.
 7. A composition for the control of undesirable vegetation consisting essentially of a compound of claim 3 and at least one of (a) a surface active agent, and (b) a solid or liquid diluent.
 8. A composition for the control of undesirable vegetation consisting essentially of a compound of claim 4 and at least one of (a) a surface active agent, and (b) a solid or liquid diluent.
 9. A method for the control of undesirable vegetation comprising applying to the locus of such vegetation an herbicidally effective amount of a compound of claim
 1. 10. A method for the control of undesirable vegetation comprising applying to the locus of such vegetation an herbicidally effective amount of a compound of claim
 2. 11. A method for the control of undesirable vegetation comprising applying to the locus of such vegetation an herbicidally effective amount of a compound of claim
 3. 12. A method for the control of undesirable vegetation comprising applying to the locus of such vegetation an herbicidally effective amount of a compound of claim
 4. 